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Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)

The tetranuclear molecules of the title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], reside on a crystallographic inversion center. Both the two independent Sn atoms are five-coordinate, with distorted trigonal–bipyramidal geometries. One Sn atom is coordinated by two O atoms of the carb...

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Detalles Bibliográficos
Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Teoh, Siang-Guan, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009280/
https://www.ncbi.nlm.nih.gov/pubmed/21588838
http://dx.doi.org/10.1107/S1600536810040146
Descripción
Sumario:The tetranuclear molecules of the title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], reside on a crystallographic inversion center. Both the two independent Sn atoms are five-coordinate, with distorted trigonal–bipyramidal geometries. One Sn atom is coordinated by two O atoms of the carboxyl­ate anions, one bridging O atom and two butyl groups and the other Sn atom is coordinated by an O atom of the carboxyl­ate anion, two bridging O atoms and two butyl groups. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. The mol­ecular structure is stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal, pairs of inter­molecular bifurcated acceptor N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains along [10[Image: see text]]. Weak inter­molecular C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.713 (2) Å] are also observed.