Cargando…
Bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(IV)
The tetranuclear molecules of the title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], reside on a crystallographic inversion center. Both the two independent Sn atoms are five-coordinate, with distorted trigonal–bipyramidal geometries. One Sn atom is coordinated by two O atoms of the carb...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009280/ https://www.ncbi.nlm.nih.gov/pubmed/21588838 http://dx.doi.org/10.1107/S1600536810040146 |
_version_ | 1782194650549846016 |
---|---|
author | Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Goh, Jia Hao Fun, Hoong-Kun |
author_facet | Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Goh, Jia Hao Fun, Hoong-Kun |
author_sort | Win, Yip-Foo |
collection | PubMed |
description | The tetranuclear molecules of the title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], reside on a crystallographic inversion center. Both the two independent Sn atoms are five-coordinate, with distorted trigonal–bipyramidal geometries. One Sn atom is coordinated by two O atoms of the carboxylate anions, one bridging O atom and two butyl groups and the other Sn atom is coordinated by an O atom of the carboxylate anion, two bridging O atoms and two butyl groups. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. The molecular structure is stabilized by intramolecular N—H⋯O hydrogen bonds. In the crystal, pairs of intermolecular bifurcated acceptor N—H⋯O and C—H⋯O hydrogen bonds link the molecules into chains along [10[Image: see text]]. Weak intermolecular C—H⋯π and π–π interactions [centroid–centroid distance = 3.713 (2) Å] are also observed. |
format | Text |
id | pubmed-3009280 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30092802010-12-30 Bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(IV) Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tetranuclear molecules of the title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], reside on a crystallographic inversion center. Both the two independent Sn atoms are five-coordinate, with distorted trigonal–bipyramidal geometries. One Sn atom is coordinated by two O atoms of the carboxylate anions, one bridging O atom and two butyl groups and the other Sn atom is coordinated by an O atom of the carboxylate anion, two bridging O atoms and two butyl groups. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. The molecular structure is stabilized by intramolecular N—H⋯O hydrogen bonds. In the crystal, pairs of intermolecular bifurcated acceptor N—H⋯O and C—H⋯O hydrogen bonds link the molecules into chains along [10[Image: see text]]. Weak intermolecular C—H⋯π and π–π interactions [centroid–centroid distance = 3.713 (2) Å] are also observed. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009280/ /pubmed/21588838 http://dx.doi.org/10.1107/S1600536810040146 Text en © Win et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Goh, Jia Hao Fun, Hoong-Kun Bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(IV) |
title | Bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(IV) |
title_full | Bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(IV) |
title_fullStr | Bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(IV) |
title_full_unstemmed | Bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(IV) |
title_short | Bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(IV) |
title_sort | bis(μ(2)-4-amino-3-nitrobenzoato)bis(4-amino-3-nitrobenzoato)octabutyldi-μ(3)-oxido-tetratin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009280/ https://www.ncbi.nlm.nih.gov/pubmed/21588838 http://dx.doi.org/10.1107/S1600536810040146 |
work_keys_str_mv | AT winyipfoo bism24amino3nitrobenzoatobis4amino3nitrobenzoatooctabutyldim3oxidotetratiniv AT choongchenshang bism24amino3nitrobenzoatobis4amino3nitrobenzoatooctabutyldim3oxidotetratiniv AT teohsiangguan bism24amino3nitrobenzoatobis4amino3nitrobenzoatooctabutyldim3oxidotetratiniv AT gohjiahao bism24amino3nitrobenzoatobis4amino3nitrobenzoatooctabutyldim3oxidotetratiniv AT funhoongkun bism24amino3nitrobenzoatobis4amino3nitrobenzoatooctabutyldim3oxidotetratiniv |