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Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)

The tetranuclear molecules of the title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], reside on a crystallographic inversion center. Both the two independent Sn atoms are five-coordinate, with distorted trigonal–bipyramidal geometries. One Sn atom is coordinated by two O atoms of the carb...

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Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Teoh, Siang-Guan, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009280/
https://www.ncbi.nlm.nih.gov/pubmed/21588838
http://dx.doi.org/10.1107/S1600536810040146
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author Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Win, Yip-Foo
collection PubMed
description The tetranuclear molecules of the title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], reside on a crystallographic inversion center. Both the two independent Sn atoms are five-coordinate, with distorted trigonal–bipyramidal geometries. One Sn atom is coordinated by two O atoms of the carboxyl­ate anions, one bridging O atom and two butyl groups and the other Sn atom is coordinated by an O atom of the carboxyl­ate anion, two bridging O atoms and two butyl groups. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. The mol­ecular structure is stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal, pairs of inter­molecular bifurcated acceptor N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains along [10[Image: see text]]. Weak inter­molecular C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.713 (2) Å] are also observed.
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spelling pubmed-30092802010-12-30 Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV) Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tetranuclear molecules of the title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], reside on a crystallographic inversion center. Both the two independent Sn atoms are five-coordinate, with distorted trigonal–bipyramidal geometries. One Sn atom is coordinated by two O atoms of the carboxyl­ate anions, one bridging O atom and two butyl groups and the other Sn atom is coordinated by an O atom of the carboxyl­ate anion, two bridging O atoms and two butyl groups. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. The mol­ecular structure is stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal, pairs of inter­molecular bifurcated acceptor N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains along [10[Image: see text]]. Weak inter­molecular C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.713 (2) Å] are also observed. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009280/ /pubmed/21588838 http://dx.doi.org/10.1107/S1600536810040146 Text en © Win et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Goh, Jia Hao
Fun, Hoong-Kun
Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_full Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_fullStr Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_full_unstemmed Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_short Bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_sort bis(μ(2)-4-amino-3-nitro­benzoato)bis­(4-amino-3-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009280/
https://www.ncbi.nlm.nih.gov/pubmed/21588838
http://dx.doi.org/10.1107/S1600536810040146
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