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3,3,9,9-Tetra­phenyl-2,4,8,10-tetra­oxa­spiro­[5.5]undeca­ne

In the title compound, C(31)H(28)O(4), the asymmetric unit contains two crystallographically independent mol­ecules. In these two mol­ecules, the four dihedral angles between each pair of phenyl rings on the same C atoms are 75.4 (1), 83.0 (1), 85.0 (1) and 80.4 (2)°. All of the nonplanar six-member...

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Detalles Bibliográficos
Autores principales: Sun, Xiaoqiang, Chen, Liang, Jiang, Yan, Li, Zhengyi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009283/
https://www.ncbi.nlm.nih.gov/pubmed/21589189
http://dx.doi.org/10.1107/S1600536810043795
Descripción
Sumario:In the title compound, C(31)H(28)O(4), the asymmetric unit contains two crystallographically independent mol­ecules. In these two mol­ecules, the four dihedral angles between each pair of phenyl rings on the same C atoms are 75.4 (1), 83.0 (1), 85.0 (1) and 80.4 (2)°. All of the nonplanar six-membered heterocycles adopt chair conformations. Inter­molecular C—H⋯π and weak C—H⋯O inter­actions link the mol­ecules and are effective in the stabilization of the crystal structure.