mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN (1)]bis­(2-quinolylphenyl-κ(2) C (1),N)iridium(III) deuterochloro­form disolvate

In the title compound, [Ir(C(13)H(9)N(4))(C(15)H(10)N)(2)]·2CDCl(3), the coordination at iridium is octa­hedral, but with narrow ligand bite angles ranging from 74.85 (8) to 83.99 (8)°. The bond lengths at iridium show the expected trans influence, with Ir—N trans to C being appreciably longer than...

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Autores principales: Jones, Peter G., Freund, Andreas, Debeaux, Marc, Kowalsky, Wolfgang, Johannes, Hans-Hermann
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009293/
https://www.ncbi.nlm.nih.gov/pubmed/21588839
http://dx.doi.org/10.1107/S1600536810038596
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author Jones, Peter G.
Freund, Andreas
Debeaux, Marc
Kowalsky, Wolfgang
Johannes, Hans-Hermann
author_facet Jones, Peter G.
Freund, Andreas
Debeaux, Marc
Kowalsky, Wolfgang
Johannes, Hans-Hermann
author_sort Jones, Peter G.
collection PubMed
description In the title compound, [Ir(C(13)H(9)N(4))(C(15)H(10)N)(2)]·2CDCl(3), the coordination at iridium is octa­hedral, but with narrow ligand bite angles ranging from 74.85 (8) to 83.99 (8)°. The bond lengths at iridium show the expected trans influence, with Ir—N trans to C being appreciably longer than trans to N. The chelate rings are mutually perpendicular to a reasonable approximation [interplanar angles ranging from 77.79 (6) to 83.93 (7)°]. All ligands are approximately planar; the maximum inter­planar angles within ligands are ca 12°. One CDCl(3) solvent molecule is severly disordered and was excluded from the refinement.
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spelling pubmed-30092932010-12-30 mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN (1)]bis­(2-quinolylphenyl-κ(2) C (1),N)iridium(III) deuterochloro­form disolvate Jones, Peter G. Freund, Andreas Debeaux, Marc Kowalsky, Wolfgang Johannes, Hans-Hermann Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(13)H(9)N(4))(C(15)H(10)N)(2)]·2CDCl(3), the coordination at iridium is octa­hedral, but with narrow ligand bite angles ranging from 74.85 (8) to 83.99 (8)°. The bond lengths at iridium show the expected trans influence, with Ir—N trans to C being appreciably longer than trans to N. The chelate rings are mutually perpendicular to a reasonable approximation [interplanar angles ranging from 77.79 (6) to 83.93 (7)°]. All ligands are approximately planar; the maximum inter­planar angles within ligands are ca 12°. One CDCl(3) solvent molecule is severly disordered and was excluded from the refinement. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009293/ /pubmed/21588839 http://dx.doi.org/10.1107/S1600536810038596 Text en © Jones et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jones, Peter G.
Freund, Andreas
Debeaux, Marc
Kowalsky, Wolfgang
Johannes, Hans-Hermann
mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN (1)]bis­(2-quinolylphenyl-κ(2) C (1),N)iridium(III) deuterochloro­form disolvate
title mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN (1)]bis­(2-quinolylphenyl-κ(2) C (1),N)iridium(III) deuterochloro­form disolvate
title_full mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN (1)]bis­(2-quinolylphenyl-κ(2) C (1),N)iridium(III) deuterochloro­form disolvate
title_fullStr mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN (1)]bis­(2-quinolylphenyl-κ(2) C (1),N)iridium(III) deuterochloro­form disolvate
title_full_unstemmed mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN (1)]bis­(2-quinolylphenyl-κ(2) C (1),N)iridium(III) deuterochloro­form disolvate
title_short mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN (1)]bis­(2-quinolylphenyl-κ(2) C (1),N)iridium(III) deuterochloro­form disolvate
title_sort mer-[3-phenyl-5-(2-pyridyl-κn)-1,2,4-triazol-1-ido-κn (1)]bis­(2-quinolylphenyl-κ(2) c (1),n)iridium(iii) deuterochloro­form disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009293/
https://www.ncbi.nlm.nih.gov/pubmed/21588839
http://dx.doi.org/10.1107/S1600536810038596
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