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catena-Poly[[cobalt(II)-μ-aqua-μ-propano­ato-κ(2) O:O′-μ-propano­ato-κ(2) O:O] monohydrate]

The title compound, {[Co(C(2)H(5)COO)(2)(H(2)O)]·H(2)O}(n), was synthesized by the reaction of cobalt(II) carbonate hydrate with aqueous propionic acid. The structure consists of polymeric infinite linear chains with composition [Co(C(2)H(5)COO)(4/2)(H(2)O)(2/2)](∞) running along [010]. The chains a...

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Detalles Bibliográficos
Autores principales: Fischer, A. I., Gurzhiy, V. V., Belyaev, A. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009297/
https://www.ncbi.nlm.nih.gov/pubmed/21588911
http://dx.doi.org/10.1107/S1600536810043540
Descripción
Sumario:The title compound, {[Co(C(2)H(5)COO)(2)(H(2)O)]·H(2)O}(n), was synthesized by the reaction of cobalt(II) carbonate hydrate with aqueous propionic acid. The structure consists of polymeric infinite linear chains with composition [Co(C(2)H(5)COO)(4/2)(H(2)O)(2/2)](∞) running along [010]. The chains are formed by Co(2+) ions linked with bridging propionate groups and water mol­ecules, with a Co⋯Co distance along the chains of 3.2587 (9) Å. The Co(2+) ion is six-coordinated in a strongly distorted octa­hedral geometry. The chains are connected to each other by a network of O—H⋯O hydrogen bonds involving solvent water mol­ecules.