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catena-Poly[[cobalt(II)-μ-aqua-μ-propanoato-κ(2) O:O′-μ-propanoato-κ(2) O:O] monohydrate]
The title compound, {[Co(C(2)H(5)COO)(2)(H(2)O)]·H(2)O}(n), was synthesized by the reaction of cobalt(II) carbonate hydrate with aqueous propionic acid. The structure consists of polymeric infinite linear chains with composition [Co(C(2)H(5)COO)(4/2)(H(2)O)(2/2)](∞) running along [010]. The chains a...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009297/ https://www.ncbi.nlm.nih.gov/pubmed/21588911 http://dx.doi.org/10.1107/S1600536810043540 |
| _version_ | 1782194654639292416 |
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| author | Fischer, A. I. Gurzhiy, V. V. Belyaev, A. N. |
| author_facet | Fischer, A. I. Gurzhiy, V. V. Belyaev, A. N. |
| author_sort | Fischer, A. I. |
| collection | PubMed |
| description | The title compound, {[Co(C(2)H(5)COO)(2)(H(2)O)]·H(2)O}(n), was synthesized by the reaction of cobalt(II) carbonate hydrate with aqueous propionic acid. The structure consists of polymeric infinite linear chains with composition [Co(C(2)H(5)COO)(4/2)(H(2)O)(2/2)](∞) running along [010]. The chains are formed by Co(2+) ions linked with bridging propionate groups and water molecules, with a Co⋯Co distance along the chains of 3.2587 (9) Å. The Co(2+) ion is six-coordinated in a strongly distorted octahedral geometry. The chains are connected to each other by a network of O—H⋯O hydrogen bonds involving solvent water molecules. |
| format | Text |
| id | pubmed-3009297 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30092972010-12-30 catena-Poly[[cobalt(II)-μ-aqua-μ-propanoato-κ(2) O:O′-μ-propanoato-κ(2) O:O] monohydrate] Fischer, A. I. Gurzhiy, V. V. Belyaev, A. N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Co(C(2)H(5)COO)(2)(H(2)O)]·H(2)O}(n), was synthesized by the reaction of cobalt(II) carbonate hydrate with aqueous propionic acid. The structure consists of polymeric infinite linear chains with composition [Co(C(2)H(5)COO)(4/2)(H(2)O)(2/2)](∞) running along [010]. The chains are formed by Co(2+) ions linked with bridging propionate groups and water molecules, with a Co⋯Co distance along the chains of 3.2587 (9) Å. The Co(2+) ion is six-coordinated in a strongly distorted octahedral geometry. The chains are connected to each other by a network of O—H⋯O hydrogen bonds involving solvent water molecules. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009297/ /pubmed/21588911 http://dx.doi.org/10.1107/S1600536810043540 Text en © Fischer et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fischer, A. I. Gurzhiy, V. V. Belyaev, A. N. catena-Poly[[cobalt(II)-μ-aqua-μ-propanoato-κ(2) O:O′-μ-propanoato-κ(2) O:O] monohydrate] |
| title |
catena-Poly[[cobalt(II)-μ-aqua-μ-propanoato-κ(2)
O:O′-μ-propanoato-κ(2)
O:O] monohydrate] |
| title_full |
catena-Poly[[cobalt(II)-μ-aqua-μ-propanoato-κ(2)
O:O′-μ-propanoato-κ(2)
O:O] monohydrate] |
| title_fullStr |
catena-Poly[[cobalt(II)-μ-aqua-μ-propanoato-κ(2)
O:O′-μ-propanoato-κ(2)
O:O] monohydrate] |
| title_full_unstemmed |
catena-Poly[[cobalt(II)-μ-aqua-μ-propanoato-κ(2)
O:O′-μ-propanoato-κ(2)
O:O] monohydrate] |
| title_short |
catena-Poly[[cobalt(II)-μ-aqua-μ-propanoato-κ(2)
O:O′-μ-propanoato-κ(2)
O:O] monohydrate] |
| title_sort | catena-poly[[cobalt(ii)-μ-aqua-μ-propanoato-κ(2)
o:o′-μ-propanoato-κ(2)
o:o] monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009297/ https://www.ncbi.nlm.nih.gov/pubmed/21588911 http://dx.doi.org/10.1107/S1600536810043540 |
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