17β-Hy­droxy-17α-(hy­droxy­meth­yl)estr-4-en-3-one

The title compound, C(19)H(28)O(3), the fungal-transformed metabolite of the steroid methyl­oestrenol contains four fused rings A, B, C and D. Ring A adopts a half-chair and the trans-fused rings B and C adopt chair confirmations; the five-membered D ring is folded like an envelope. In the crystal,...

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Detalles Bibliográficos
Autores principales: Yousuf, Sammer, Zafar, Salman, Choudhary, Muhammed Iqbal, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009298/
https://www.ncbi.nlm.nih.gov/pubmed/21589072
http://dx.doi.org/10.1107/S160053681004033X
Descripción
Sumario:The title compound, C(19)H(28)O(3), the fungal-transformed metabolite of the steroid methyl­oestrenol contains four fused rings A, B, C and D. Ring A adopts a half-chair and the trans-fused rings B and C adopt chair confirmations; the five-membered D ring is folded like an envelope. In the crystal, adjacent mol­ecules are linked by O—H⋯O(carbon­yl) and O—H⋯O(hy­droxy) hydrogen bonds into a layer structure.

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