Diazido­(2,2′-bipyrid­yl)dimethanol­nickel(II)

The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octa­hedral environment by two azide ligands in a trans configuration. The methanol l...

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Detalles Bibliográficos
Autores principales: Li, Hong-Gang, Li, Shao-Ying, Shao, Li-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009301/
https://www.ncbi.nlm.nih.gov/pubmed/21588795
http://dx.doi.org/10.1107/S1600536810038377
Descripción
Sumario:The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octa­hedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hy­droxy groups form intra­molecular O—H⋯(N,N) hydrogen bonds with the azide ligands.

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