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Diazido(2,2′-bipyridyl)dimethanolnickel(II)
The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octahedral environment by two azide ligands in a trans configuration. The methanol l...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009301/ https://www.ncbi.nlm.nih.gov/pubmed/21588795 http://dx.doi.org/10.1107/S1600536810038377 |
| _version_ | 1782194655603982336 |
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| author | Li, Hong-Gang Li, Shao-Ying Shao, Li-Jun |
| author_facet | Li, Hong-Gang Li, Shao-Ying Shao, Li-Jun |
| author_sort | Li, Hong-Gang |
| collection | PubMed |
| description | The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octahedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hydroxy groups form intramolecular O—H⋯(N,N) hydrogen bonds with the azide ligands. |
| format | Text |
| id | pubmed-3009301 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30093012010-12-30 Diazido(2,2′-bipyridyl)dimethanolnickel(II) Li, Hong-Gang Li, Shao-Ying Shao, Li-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octahedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hydroxy groups form intramolecular O—H⋯(N,N) hydrogen bonds with the azide ligands. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009301/ /pubmed/21588795 http://dx.doi.org/10.1107/S1600536810038377 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Hong-Gang Li, Shao-Ying Shao, Li-Jun Diazido(2,2′-bipyridyl)dimethanolnickel(II) |
| title | Diazido(2,2′-bipyridyl)dimethanolnickel(II) |
| title_full | Diazido(2,2′-bipyridyl)dimethanolnickel(II) |
| title_fullStr | Diazido(2,2′-bipyridyl)dimethanolnickel(II) |
| title_full_unstemmed | Diazido(2,2′-bipyridyl)dimethanolnickel(II) |
| title_short | Diazido(2,2′-bipyridyl)dimethanolnickel(II) |
| title_sort | diazido(2,2′-bipyridyl)dimethanolnickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009301/ https://www.ncbi.nlm.nih.gov/pubmed/21588795 http://dx.doi.org/10.1107/S1600536810038377 |
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