(5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) trihydrate

The Co(II) atom in the title compound, [Co(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in a CoN(3)O(3) octa­hedral geometry; the water-coordinated Co(II) atom is chelated by the N-heterocycle. An inter­molecular N—H⋯O hydrogen bond occurs. The carboxyl­ate entity coordinates...

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Detalles Bibliográficos
Autores principales: Zhang, Kou-Lin, Diao, Guo-Wang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009302/
https://www.ncbi.nlm.nih.gov/pubmed/21588848
http://dx.doi.org/10.1107/S1600536810040560
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author Zhang, Kou-Lin
Diao, Guo-Wang
Ng, Seik Weng
author_facet Zhang, Kou-Lin
Diao, Guo-Wang
Ng, Seik Weng
author_sort Zhang, Kou-Lin
collection PubMed
description The Co(II) atom in the title compound, [Co(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in a CoN(3)O(3) octa­hedral geometry; the water-coordinated Co(II) atom is chelated by the N-heterocycle. An inter­molecular N—H⋯O hydrogen bond occurs. The carboxyl­ate entity coordinates through the amino group. The carboxyl­ate donor unit, coordinated and uncoordinated water mol­ecules inter­act through O—H⋯O and N—H⋯O hydrogen bonds, generating a tightly-held three-dimensional cage-like network.
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spelling pubmed-30093022010-12-30 (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) trihydrate Zhang, Kou-Lin Diao, Guo-Wang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(II) atom in the title compound, [Co(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in a CoN(3)O(3) octa­hedral geometry; the water-coordinated Co(II) atom is chelated by the N-heterocycle. An inter­molecular N—H⋯O hydrogen bond occurs. The carboxyl­ate entity coordinates through the amino group. The carboxyl­ate donor unit, coordinated and uncoordinated water mol­ecules inter­act through O—H⋯O and N—H⋯O hydrogen bonds, generating a tightly-held three-dimensional cage-like network. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009302/ /pubmed/21588848 http://dx.doi.org/10.1107/S1600536810040560 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Kou-Lin
Diao, Guo-Wang
Ng, Seik Weng
(5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) trihydrate
title (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) trihydrate
title_full (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) trihydrate
title_fullStr (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) trihydrate
title_full_unstemmed (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) trihydrate
title_short (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) trihydrate
title_sort (5-amino­isophthalato-κn)triaqua­(1,10-phenanthroline-κ(2) n,n′)cobalt(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009302/
https://www.ncbi.nlm.nih.gov/pubmed/21588848
http://dx.doi.org/10.1107/S1600536810040560
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AT ngseikweng 5aminoisophthalatokntriaqua110phenanthrolinek2nncobaltiitrihydrate

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