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(Di-2-pyridyl­amine)­(methanol)sulfato­copper(II)

The title complex, [Cu(SO(4))(C(10)H(9)N(3))(CH(3)OH)], is a mononuclear species with the Cu(II) ion in a Jahn–Teller-distorted ‘4 + 1’ square-pyramidal geometry. The basal plane is defined by the pyridyl N-atom donors of the bipyridyl­amine (bpa) ligand and two O-atom donors of the sulfate ligand....

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Autores principales: DeBurgomaster, Paul, Zubieta, Jon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009304/
https://www.ncbi.nlm.nih.gov/pubmed/21588796
http://dx.doi.org/10.1107/S1600536810038675
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author DeBurgomaster, Paul
Zubieta, Jon
author_facet DeBurgomaster, Paul
Zubieta, Jon
author_sort DeBurgomaster, Paul
collection PubMed
description The title complex, [Cu(SO(4))(C(10)H(9)N(3))(CH(3)OH)], is a mononuclear species with the Cu(II) ion in a Jahn–Teller-distorted ‘4 + 1’ square-pyramidal geometry. The basal plane is defined by the pyridyl N-atom donors of the bipyridyl­amine (bpa) ligand and two O-atom donors of the sulfate ligand. The coordination geometry is completed by the axial coordination of a methanol O-atom donor. The axial bond length displays the usual elongation: Cu—O(axial) = 2.168 (2), Cu—O(basal) = 2.016 (2) (average) and Cu—N(basal) = 1.951 (3) Å (average). In the crystal structure, the complex mol­ecules are linked through N—H⋯O and O—H⋯O hydrogen bonds into chains along [100].
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spelling pubmed-30093042010-12-30 (Di-2-pyridyl­amine)­(methanol)sulfato­copper(II) DeBurgomaster, Paul Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(SO(4))(C(10)H(9)N(3))(CH(3)OH)], is a mononuclear species with the Cu(II) ion in a Jahn–Teller-distorted ‘4 + 1’ square-pyramidal geometry. The basal plane is defined by the pyridyl N-atom donors of the bipyridyl­amine (bpa) ligand and two O-atom donors of the sulfate ligand. The coordination geometry is completed by the axial coordination of a methanol O-atom donor. The axial bond length displays the usual elongation: Cu—O(axial) = 2.168 (2), Cu—O(basal) = 2.016 (2) (average) and Cu—N(basal) = 1.951 (3) Å (average). In the crystal structure, the complex mol­ecules are linked through N—H⋯O and O—H⋯O hydrogen bonds into chains along [100]. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009304/ /pubmed/21588796 http://dx.doi.org/10.1107/S1600536810038675 Text en © DeBurgomaster and Zubieta 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
DeBurgomaster, Paul
Zubieta, Jon
(Di-2-pyridyl­amine)­(methanol)sulfato­copper(II)
title (Di-2-pyridyl­amine)­(methanol)sulfato­copper(II)
title_full (Di-2-pyridyl­amine)­(methanol)sulfato­copper(II)
title_fullStr (Di-2-pyridyl­amine)­(methanol)sulfato­copper(II)
title_full_unstemmed (Di-2-pyridyl­amine)­(methanol)sulfato­copper(II)
title_short (Di-2-pyridyl­amine)­(methanol)sulfato­copper(II)
title_sort (di-2-pyridyl­amine)­(methanol)sulfato­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009304/
https://www.ncbi.nlm.nih.gov/pubmed/21588796
http://dx.doi.org/10.1107/S1600536810038675
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