Cargando…
(Di-2-pyridylamine)(methanol)sulfatocopper(II)
The title complex, [Cu(SO(4))(C(10)H(9)N(3))(CH(3)OH)], is a mononuclear species with the Cu(II) ion in a Jahn–Teller-distorted ‘4 + 1’ square-pyramidal geometry. The basal plane is defined by the pyridyl N-atom donors of the bipyridylamine (bpa) ligand and two O-atom donors of the sulfate ligand....
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009304/ https://www.ncbi.nlm.nih.gov/pubmed/21588796 http://dx.doi.org/10.1107/S1600536810038675 |
_version_ | 1782194656327499776 |
---|---|
author | DeBurgomaster, Paul Zubieta, Jon |
author_facet | DeBurgomaster, Paul Zubieta, Jon |
author_sort | DeBurgomaster, Paul |
collection | PubMed |
description | The title complex, [Cu(SO(4))(C(10)H(9)N(3))(CH(3)OH)], is a mononuclear species with the Cu(II) ion in a Jahn–Teller-distorted ‘4 + 1’ square-pyramidal geometry. The basal plane is defined by the pyridyl N-atom donors of the bipyridylamine (bpa) ligand and two O-atom donors of the sulfate ligand. The coordination geometry is completed by the axial coordination of a methanol O-atom donor. The axial bond length displays the usual elongation: Cu—O(axial) = 2.168 (2), Cu—O(basal) = 2.016 (2) (average) and Cu—N(basal) = 1.951 (3) Å (average). In the crystal structure, the complex molecules are linked through N—H⋯O and O—H⋯O hydrogen bonds into chains along [100]. |
format | Text |
id | pubmed-3009304 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30093042010-12-30 (Di-2-pyridylamine)(methanol)sulfatocopper(II) DeBurgomaster, Paul Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(SO(4))(C(10)H(9)N(3))(CH(3)OH)], is a mononuclear species with the Cu(II) ion in a Jahn–Teller-distorted ‘4 + 1’ square-pyramidal geometry. The basal plane is defined by the pyridyl N-atom donors of the bipyridylamine (bpa) ligand and two O-atom donors of the sulfate ligand. The coordination geometry is completed by the axial coordination of a methanol O-atom donor. The axial bond length displays the usual elongation: Cu—O(axial) = 2.168 (2), Cu—O(basal) = 2.016 (2) (average) and Cu—N(basal) = 1.951 (3) Å (average). In the crystal structure, the complex molecules are linked through N—H⋯O and O—H⋯O hydrogen bonds into chains along [100]. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009304/ /pubmed/21588796 http://dx.doi.org/10.1107/S1600536810038675 Text en © DeBurgomaster and Zubieta 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers DeBurgomaster, Paul Zubieta, Jon (Di-2-pyridylamine)(methanol)sulfatocopper(II) |
title | (Di-2-pyridylamine)(methanol)sulfatocopper(II) |
title_full | (Di-2-pyridylamine)(methanol)sulfatocopper(II) |
title_fullStr | (Di-2-pyridylamine)(methanol)sulfatocopper(II) |
title_full_unstemmed | (Di-2-pyridylamine)(methanol)sulfatocopper(II) |
title_short | (Di-2-pyridylamine)(methanol)sulfatocopper(II) |
title_sort | (di-2-pyridylamine)(methanol)sulfatocopper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009304/ https://www.ncbi.nlm.nih.gov/pubmed/21588796 http://dx.doi.org/10.1107/S1600536810038675 |
work_keys_str_mv | AT deburgomasterpaul di2pyridylaminemethanolsulfatocopperii AT zubietajon di2pyridylaminemethanolsulfatocopperii |