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Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3) O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate
In the title compound, [Mn(C(13)H(8)N(3)O(3))(2)]·C(3)H(7)NO·H(2)O, the metal atom is O,N,O′-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N–H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N—H⋯O and O—...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009305/ https://www.ncbi.nlm.nih.gov/pubmed/21588862 http://dx.doi.org/10.1107/S1600536810039516 |
Sumario: | In the title compound, [Mn(C(13)H(8)N(3)O(3))(2)]·C(3)H(7)NO·H(2)O, the metal atom is O,N,O′-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N–H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N—H⋯O and O—H⋯O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. |
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