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Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3) O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate
In the title compound, [Mn(C(13)H(8)N(3)O(3))(2)]·C(3)H(7)NO·H(2)O, the metal atom is O,N,O′-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N–H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N—H⋯O and O—...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009305/ https://www.ncbi.nlm.nih.gov/pubmed/21588862 http://dx.doi.org/10.1107/S1600536810039516 |
| _version_ | 1782194656580206592 |
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| author | Abdul Halim, Siti Nadiah Ali, Hapipah Mohd Ng, Seik Weng |
| author_facet | Abdul Halim, Siti Nadiah Ali, Hapipah Mohd Ng, Seik Weng |
| author_sort | Abdul Halim, Siti Nadiah |
| collection | PubMed |
| description | In the title compound, [Mn(C(13)H(8)N(3)O(3))(2)]·C(3)H(7)NO·H(2)O, the metal atom is O,N,O′-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N–H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N—H⋯O and O—H⋯O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. |
| format | Text |
| id | pubmed-3009305 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30093052010-12-30 Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3) O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate Abdul Halim, Siti Nadiah Ali, Hapipah Mohd Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(13)H(8)N(3)O(3))(2)]·C(3)H(7)NO·H(2)O, the metal atom is O,N,O′-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N–H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N—H⋯O and O—H⋯O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009305/ /pubmed/21588862 http://dx.doi.org/10.1107/S1600536810039516 Text en © Abdul Halim et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Abdul Halim, Siti Nadiah Ali, Hapipah Mohd Ng, Seik Weng Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3) O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title | Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3)
O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_full | Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3)
O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_fullStr | Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3)
O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_full_unstemmed | Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3)
O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_short | Bis[N′-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κ(3)
O,N′,O′]manganese(II) N,N-dimethylformide monosolvate monohydrate |
| title_sort | bis[n′-(2-oxo-1h-indol-3-ylidene)furan-2-carbohydrazidato-κ(3)
o,n′,o′]manganese(ii) n,n-dimethylformide monosolvate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009305/ https://www.ncbi.nlm.nih.gov/pubmed/21588862 http://dx.doi.org/10.1107/S1600536810039516 |
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