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1-(4-Bromo-2-fluorobenzyl)pyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III)
The title compound, (C(12)H(10)BrFN)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of N-(2-fluoro-4-bromobenzyl)pyridinium cations and [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009307/ https://www.ncbi.nlm.nih.gov/pubmed/21588808 http://dx.doi.org/10.1107/S1600536810039334 |
| Sumario: | The title compound, (C(12)H(10)BrFN)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of N-(2-fluoro-4-bromobenzyl)pyridinium cations and [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal structure, weak S⋯S [3.474 (3), 3.478 (3) and 3.547 (3) Å] and S⋯π [S⋯centroid distances = 3.360 (3), 3.378 (2), 3.537 (2) and 3.681 (3) Å] interactions and C—H⋯F hydrogen bonds lead to a three-dimensional supramolecular network. |
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