1-(4-Bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(III)

The title compound, (C(12)H(10)BrFN)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of N-(2-fluoro-4-bromo­benz­yl)pyridinium cations and [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S...

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Detalles Bibliográficos
Autores principales: Zhang, Peng, Li, Kaihui, Mei, Chongzhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009307/
https://www.ncbi.nlm.nih.gov/pubmed/21588808
http://dx.doi.org/10.1107/S1600536810039334
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author Zhang, Peng
Li, Kaihui
Mei, Chongzhen
author_facet Zhang, Peng
Li, Kaihui
Mei, Chongzhen
author_sort Zhang, Peng
collection PubMed
description The title compound, (C(12)H(10)BrFN)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of N-(2-fluoro-4-bromo­benz­yl)pyridinium cations and [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal structure, weak S⋯S [3.474 (3), 3.478 (3) and 3.547 (3) Å] and S⋯π [S⋯centroid distances = 3.360 (3), 3.378 (2), 3.537 (2) and 3.681 (3) Å] inter­actions and C—H⋯F hydrogen bonds lead to a three-dimensional supra­molecular network.
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spelling pubmed-30093072010-12-30 1-(4-Bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(III) Zhang, Peng Li, Kaihui Mei, Chongzhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(12)H(10)BrFN)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of N-(2-fluoro-4-bromo­benz­yl)pyridinium cations and [Ni(dmit)(2)](−) anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal structure, weak S⋯S [3.474 (3), 3.478 (3) and 3.547 (3) Å] and S⋯π [S⋯centroid distances = 3.360 (3), 3.378 (2), 3.537 (2) and 3.681 (3) Å] inter­actions and C—H⋯F hydrogen bonds lead to a three-dimensional supra­molecular network. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009307/ /pubmed/21588808 http://dx.doi.org/10.1107/S1600536810039334 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Peng
Li, Kaihui
Mei, Chongzhen
1-(4-Bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(III)
title 1-(4-Bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(III)
title_full 1-(4-Bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(III)
title_fullStr 1-(4-Bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(III)
title_full_unstemmed 1-(4-Bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(III)
title_short 1-(4-Bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(III)
title_sort 1-(4-bromo-2-fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickelate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009307/
https://www.ncbi.nlm.nih.gov/pubmed/21588808
http://dx.doi.org/10.1107/S1600536810039334
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AT likaihui 14bromo2fluorobenzylpyridiniumbis2thioxo13dithiole45dithiolatonickelateiii
AT meichongzhen 14bromo2fluorobenzylpyridiniumbis2thioxo13dithiole45dithiolatonickelateiii

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