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n-Butyldichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(IV)
Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C(4)H(9))(C(13)H(12)N(3)O)Cl(2)]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming five- and six-membered chelate rings. The approximately octa...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009310/ https://www.ncbi.nlm.nih.gov/pubmed/21588842 http://dx.doi.org/10.1107/S1600536810040572 |
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author | Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Affan, Md. Abu |
collection | PubMed |
description | Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C(4)H(9))(C(13)H(12)N(3)O)Cl(2)]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming five- and six-membered chelate rings. The approximately octahedral coordination geometry is completed by the α-C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the molecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and −64.4 (11)°]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H⋯Cl hydrogen bonds, which link the molecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H⋯Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%. |
format | Text |
id | pubmed-3009310 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30093102010-12-30 n-Butyldichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(IV) Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C(4)H(9))(C(13)H(12)N(3)O)Cl(2)]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming five- and six-membered chelate rings. The approximately octahedral coordination geometry is completed by the α-C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the molecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and −64.4 (11)°]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H⋯Cl hydrogen bonds, which link the molecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H⋯Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009310/ /pubmed/21588842 http://dx.doi.org/10.1107/S1600536810040572 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Ng, Seik Weng Tiekink, Edward R. T. n-Butyldichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(IV) |
title |
n-Butyldichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(IV) |
title_full |
n-Butyldichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(IV) |
title_fullStr |
n-Butyldichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(IV) |
title_full_unstemmed |
n-Butyldichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(IV) |
title_short |
n-Butyldichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(IV) |
title_sort | n-butyldichlorido(2-{(1e)-1-[2-(pyridin-2-yl)hydrazin-1-ylidene]ethyl}phenolato)tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009310/ https://www.ncbi.nlm.nih.gov/pubmed/21588842 http://dx.doi.org/10.1107/S1600536810040572 |
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