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n-Butyl­dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(IV)

Two independent mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(4)H(9))(C(13)H(12)N(3)O)Cl(2)]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming five- and six-membered chelate rings. The approximately octa­...

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Autores principales: Affan, Md. Abu, Chee, Dayang N. A., Ahmad, Fasihuddin B., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009310/
https://www.ncbi.nlm.nih.gov/pubmed/21588842
http://dx.doi.org/10.1107/S1600536810040572
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author Affan, Md. Abu
Chee, Dayang N. A.
Ahmad, Fasihuddin B.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Affan, Md. Abu
Chee, Dayang N. A.
Ahmad, Fasihuddin B.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Affan, Md. Abu
collection PubMed
description Two independent mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(4)H(9))(C(13)H(12)N(3)O)Cl(2)]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming five- and six-membered chelate rings. The approximately octa­hedral coordination geometry is completed by the α-C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the mol­ecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and −64.4 (11)°]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H⋯Cl hydrogen bonds, which link the mol­ecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H⋯Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%.
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spelling pubmed-30093102010-12-30 n-Butyl­dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(IV) Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(4)H(9))(C(13)H(12)N(3)O)Cl(2)]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming five- and six-membered chelate rings. The approximately octa­hedral coordination geometry is completed by the α-C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the mol­ecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and −64.4 (11)°]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H⋯Cl hydrogen bonds, which link the mol­ecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H⋯Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009310/ /pubmed/21588842 http://dx.doi.org/10.1107/S1600536810040572 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Affan, Md. Abu
Chee, Dayang N. A.
Ahmad, Fasihuddin B.
Ng, Seik Weng
Tiekink, Edward R. T.
n-Butyl­dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(IV)
title n-Butyl­dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(IV)
title_full n-Butyl­dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(IV)
title_fullStr n-Butyl­dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(IV)
title_full_unstemmed n-Butyl­dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(IV)
title_short n-Butyl­dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(IV)
title_sort n-butyl­dichlorido(2-{(1e)-1-[2-(pyridin-2-yl)hydrazin-1-yl­idene]eth­yl}phenolato)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009310/
https://www.ncbi.nlm.nih.gov/pubmed/21588842
http://dx.doi.org/10.1107/S1600536810040572
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