Cargando…

5-[(E)-(2,6-Dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid

There are two geometrically different mol­ecules in the asymmetric unit of the title compound, C(14)H(9)Cl(2)NO(3). The 5-amino-2-hy­droxy­benzoic acid units [r.m.s. deviations of 0.0323 and 0.0414 Å] and 2,6-dichloro­benzaldehyde groups [r.m.s. deviations of 0.0285 and 0.0226 Å] are roughly planar...

Descripción completa

Detalles Bibliográficos
Autores principales: Tahir, M. Nawaz, Shad, Hazoor Ahmad, Khan, Muhammad Naeem, Tariq, Muhammad Ilyas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009312/
https://www.ncbi.nlm.nih.gov/pubmed/21589097
http://dx.doi.org/10.1107/S160053681004136X
_version_ 1782194658235908096
author Tahir, M. Nawaz
Shad, Hazoor Ahmad
Khan, Muhammad Naeem
Tariq, Muhammad Ilyas
author_facet Tahir, M. Nawaz
Shad, Hazoor Ahmad
Khan, Muhammad Naeem
Tariq, Muhammad Ilyas
author_sort Tahir, M. Nawaz
collection PubMed
description There are two geometrically different mol­ecules in the asymmetric unit of the title compound, C(14)H(9)Cl(2)NO(3). The 5-amino-2-hy­droxy­benzoic acid units [r.m.s. deviations of 0.0323 and 0.0414 Å] and 2,6-dichloro­benzaldehyde groups [r.m.s. deviations of 0.0285 and 0.0226 Å] are roughly planar and oriented at dihedral angles of 11.69 (13) and 83.12 (6)° in the two mol­ecules. An intra­molecular O—H⋯O hydrogen bond completes an S(6) ring motif in each mol­ecule. The two mol­ecules form dimers with each other through inter­molecular O—H⋯N and C—H⋯O hydrogen bonds, completing an R (2) (2)(8) ring motif. The dimers are inter­linked via inter­molecular O—H⋯N and C—H⋯O hydrogen bonds, forming polymeric sheets.
format Text
id pubmed-3009312
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30093122010-12-30 5-[(E)-(2,6-Dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid Tahir, M. Nawaz Shad, Hazoor Ahmad Khan, Muhammad Naeem Tariq, Muhammad Ilyas Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two geometrically different mol­ecules in the asymmetric unit of the title compound, C(14)H(9)Cl(2)NO(3). The 5-amino-2-hy­droxy­benzoic acid units [r.m.s. deviations of 0.0323 and 0.0414 Å] and 2,6-dichloro­benzaldehyde groups [r.m.s. deviations of 0.0285 and 0.0226 Å] are roughly planar and oriented at dihedral angles of 11.69 (13) and 83.12 (6)° in the two mol­ecules. An intra­molecular O—H⋯O hydrogen bond completes an S(6) ring motif in each mol­ecule. The two mol­ecules form dimers with each other through inter­molecular O—H⋯N and C—H⋯O hydrogen bonds, completing an R (2) (2)(8) ring motif. The dimers are inter­linked via inter­molecular O—H⋯N and C—H⋯O hydrogen bonds, forming polymeric sheets. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009312/ /pubmed/21589097 http://dx.doi.org/10.1107/S160053681004136X Text en © Tahir et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tahir, M. Nawaz
Shad, Hazoor Ahmad
Khan, Muhammad Naeem
Tariq, Muhammad Ilyas
5-[(E)-(2,6-Dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid
title 5-[(E)-(2,6-Dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid
title_full 5-[(E)-(2,6-Dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid
title_fullStr 5-[(E)-(2,6-Dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid
title_full_unstemmed 5-[(E)-(2,6-Dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid
title_short 5-[(E)-(2,6-Dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid
title_sort 5-[(e)-(2,6-dichloro­benzyl­idene)amino]-2-hy­droxy­benzoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009312/
https://www.ncbi.nlm.nih.gov/pubmed/21589097
http://dx.doi.org/10.1107/S160053681004136X
work_keys_str_mv AT tahirmnawaz 5e26dichlorobenzylideneamino2hydroxybenzoicacid
AT shadhazoorahmad 5e26dichlorobenzylideneamino2hydroxybenzoicacid
AT khanmuhammadnaeem 5e26dichlorobenzylideneamino2hydroxybenzoicacid
AT tariqmuhammadilyas 5e26dichlorobenzylideneamino2hydroxybenzoicacid