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5-[(E)-(2,6-Dichlorobenzylidene)amino]-2-hydroxybenzoic acid
There are two geometrically different molecules in the asymmetric unit of the title compound, C(14)H(9)Cl(2)NO(3). The 5-amino-2-hydroxybenzoic acid units [r.m.s. deviations of 0.0323 and 0.0414 Å] and 2,6-dichlorobenzaldehyde groups [r.m.s. deviations of 0.0285 and 0.0226 Å] are roughly planar...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009312/ https://www.ncbi.nlm.nih.gov/pubmed/21589097 http://dx.doi.org/10.1107/S160053681004136X |
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author | Tahir, M. Nawaz Shad, Hazoor Ahmad Khan, Muhammad Naeem Tariq, Muhammad Ilyas |
author_facet | Tahir, M. Nawaz Shad, Hazoor Ahmad Khan, Muhammad Naeem Tariq, Muhammad Ilyas |
author_sort | Tahir, M. Nawaz |
collection | PubMed |
description | There are two geometrically different molecules in the asymmetric unit of the title compound, C(14)H(9)Cl(2)NO(3). The 5-amino-2-hydroxybenzoic acid units [r.m.s. deviations of 0.0323 and 0.0414 Å] and 2,6-dichlorobenzaldehyde groups [r.m.s. deviations of 0.0285 and 0.0226 Å] are roughly planar and oriented at dihedral angles of 11.69 (13) and 83.12 (6)° in the two molecules. An intramolecular O—H⋯O hydrogen bond completes an S(6) ring motif in each molecule. The two molecules form dimers with each other through intermolecular O—H⋯N and C—H⋯O hydrogen bonds, completing an R (2) (2)(8) ring motif. The dimers are interlinked via intermolecular O—H⋯N and C—H⋯O hydrogen bonds, forming polymeric sheets. |
format | Text |
id | pubmed-3009312 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30093122010-12-30 5-[(E)-(2,6-Dichlorobenzylidene)amino]-2-hydroxybenzoic acid Tahir, M. Nawaz Shad, Hazoor Ahmad Khan, Muhammad Naeem Tariq, Muhammad Ilyas Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two geometrically different molecules in the asymmetric unit of the title compound, C(14)H(9)Cl(2)NO(3). The 5-amino-2-hydroxybenzoic acid units [r.m.s. deviations of 0.0323 and 0.0414 Å] and 2,6-dichlorobenzaldehyde groups [r.m.s. deviations of 0.0285 and 0.0226 Å] are roughly planar and oriented at dihedral angles of 11.69 (13) and 83.12 (6)° in the two molecules. An intramolecular O—H⋯O hydrogen bond completes an S(6) ring motif in each molecule. The two molecules form dimers with each other through intermolecular O—H⋯N and C—H⋯O hydrogen bonds, completing an R (2) (2)(8) ring motif. The dimers are interlinked via intermolecular O—H⋯N and C—H⋯O hydrogen bonds, forming polymeric sheets. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009312/ /pubmed/21589097 http://dx.doi.org/10.1107/S160053681004136X Text en © Tahir et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tahir, M. Nawaz Shad, Hazoor Ahmad Khan, Muhammad Naeem Tariq, Muhammad Ilyas 5-[(E)-(2,6-Dichlorobenzylidene)amino]-2-hydroxybenzoic acid |
title | 5-[(E)-(2,6-Dichlorobenzylidene)amino]-2-hydroxybenzoic acid |
title_full | 5-[(E)-(2,6-Dichlorobenzylidene)amino]-2-hydroxybenzoic acid |
title_fullStr | 5-[(E)-(2,6-Dichlorobenzylidene)amino]-2-hydroxybenzoic acid |
title_full_unstemmed | 5-[(E)-(2,6-Dichlorobenzylidene)amino]-2-hydroxybenzoic acid |
title_short | 5-[(E)-(2,6-Dichlorobenzylidene)amino]-2-hydroxybenzoic acid |
title_sort | 5-[(e)-(2,6-dichlorobenzylidene)amino]-2-hydroxybenzoic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009312/ https://www.ncbi.nlm.nih.gov/pubmed/21589097 http://dx.doi.org/10.1107/S160053681004136X |
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