Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3) O,N′,O′]zinc(II) N,N-dimethyl­formide mono­solvate monohydrate

The metal atom of the title compound, [Zn(C(13)H(8)N(3)O(2)S)(2)]·C(3)H(7)NO·H(2)O, is O,N,O′-chelated by two deprotonated Schiff bases and it exists in a distorted octa­hedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF mol­ecule and uncoordinated water mol­ecule engage i...

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Detalles Bibliográficos
Autores principales: Abdul Halim, Siti Nadiah, Ali, Hapipah Mohd, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009315/
https://www.ncbi.nlm.nih.gov/pubmed/21588861
http://dx.doi.org/10.1107/S1600536810039504
Descripción
Sumario:The metal atom of the title compound, [Zn(C(13)H(8)N(3)O(2)S)(2)]·C(3)H(7)NO·H(2)O, is O,N,O′-chelated by two deprotonated Schiff bases and it exists in a distorted octa­hedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF mol­ecule and uncoordinated water mol­ecule engage in N—H⋯O and O—H⋯O inter­actions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio.

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