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Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3) O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate
The metal atom of the title compound, [Zn(C(13)H(8)N(3)O(2)S)(2)]·C(3)H(7)NO·H(2)O, is O,N,O′-chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage i...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009315/ https://www.ncbi.nlm.nih.gov/pubmed/21588861 http://dx.doi.org/10.1107/S1600536810039504 |
| _version_ | 1782194658929016832 |
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| author | Abdul Halim, Siti Nadiah Ali, Hapipah Mohd Ng, Seik Weng |
| author_facet | Abdul Halim, Siti Nadiah Ali, Hapipah Mohd Ng, Seik Weng |
| author_sort | Abdul Halim, Siti Nadiah |
| collection | PubMed |
| description | The metal atom of the title compound, [Zn(C(13)H(8)N(3)O(2)S)(2)]·C(3)H(7)NO·H(2)O, is O,N,O′-chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N—H⋯O and O—H⋯O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. |
| format | Text |
| id | pubmed-3009315 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30093152010-12-30 Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3) O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate Abdul Halim, Siti Nadiah Ali, Hapipah Mohd Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The metal atom of the title compound, [Zn(C(13)H(8)N(3)O(2)S)(2)]·C(3)H(7)NO·H(2)O, is O,N,O′-chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N—H⋯O and O—H⋯O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009315/ /pubmed/21588861 http://dx.doi.org/10.1107/S1600536810039504 Text en © Abdul Halim et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Abdul Halim, Siti Nadiah Ali, Hapipah Mohd Ng, Seik Weng Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3) O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title | Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3)
O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_full | Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3)
O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_fullStr | Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3)
O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_full_unstemmed | Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3)
O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_short | Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3)
O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_sort | bis[n′-(2-oxo-1h-indol-3-ylidene)thiophene-2-carbohydrazidato-κ(3)
o,n′,o′]zinc(ii) n,n-dimethylformide monosolvate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009315/ https://www.ncbi.nlm.nih.gov/pubmed/21588861 http://dx.doi.org/10.1107/S1600536810039504 |
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