[2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate

The title compound, [Cr(C(27)H(26)P(2))(CO)(4)]·CH(2)Cl(2), was obtained by the reaction of Ph(2)PCMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by substitution of two carbonyl ligands. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa­hedral, with a P—Cr—P bite angle of 70.27 ...

Descripción completa

Detalles Bibliográficos
Autores principales: Peulecke, Normen, Peitz, Stephan, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009317/
https://www.ncbi.nlm.nih.gov/pubmed/21588908
http://dx.doi.org/10.1107/S1600536810043692
Descripción
Sumario:The title compound, [Cr(C(27)H(26)P(2))(CO)(4)]·CH(2)Cl(2), was obtained by the reaction of Ph(2)PCMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by substitution of two carbonyl ligands. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa­hedral, with a P—Cr—P bite angle of 70.27 (2)°.

Ejemplares similares