[2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate

The title compound, [Cr(C(27)H(26)P(2))(CO)(4)]·CH(2)Cl(2), was obtained by the reaction of Ph(2)PCMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by substitution of two carbonyl ligands. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa­hedral, with a P—Cr—P bite angle of 70.27 ...

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Detalles Bibliográficos
Autores principales: Peulecke, Normen, Peitz, Stephan, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009317/
https://www.ncbi.nlm.nih.gov/pubmed/21588908
http://dx.doi.org/10.1107/S1600536810043692
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author Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_facet Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_sort Peulecke, Normen
collection PubMed
description The title compound, [Cr(C(27)H(26)P(2))(CO)(4)]·CH(2)Cl(2), was obtained by the reaction of Ph(2)PCMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by substitution of two carbonyl ligands. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa­hedral, with a P—Cr—P bite angle of 70.27 (2)°.
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spelling pubmed-30093172010-12-30 [2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate Peulecke, Normen Peitz, Stephan Müller, Bernd H. Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cr(C(27)H(26)P(2))(CO)(4)]·CH(2)Cl(2), was obtained by the reaction of Ph(2)PCMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by substitution of two carbonyl ligands. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa­hedral, with a P—Cr—P bite angle of 70.27 (2)°. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009317/ /pubmed/21588908 http://dx.doi.org/10.1107/S1600536810043692 Text en © Peulecke et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
[2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate
title [2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate
title_full [2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate
title_fullStr [2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate
title_full_unstemmed [2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate
title_short [2,2-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate
title_sort [2,2-bis(diphenyl­phosphan­yl)propane-κ(2) p,p′]tetra­carbonyl­chromium(0) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009317/
https://www.ncbi.nlm.nih.gov/pubmed/21588908
http://dx.doi.org/10.1107/S1600536810043692
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AT peitzstephan 22bisdiphenylphosphanylpropanek2pptetracarbonylchromium0dichloromethanemonosolvate
AT mullerberndh 22bisdiphenylphosphanylpropanek2pptetracarbonylchromium0dichloromethanemonosolvate
AT spannenberganke 22bisdiphenylphosphanylpropanek2pptetracarbonylchromium0dichloromethanemonosolvate
AT rosenthaluwe 22bisdiphenylphosphanylpropanek2pptetracarbonylchromium0dichloromethanemonosolvate

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