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catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido]
The asymmetric unit of the title compound, [CdCl(2)(C(8)H(6)N(2)O)(2)](n), consists of one molecule of the 3H-quinazolin-4-one ligand, one Cd(2+) cation, which is located on a twofold axis, and one chlorido ligand in a general position. The latter bridges metal cations, forming a one-dimensional po...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009324/ https://www.ncbi.nlm.nih.gov/pubmed/21588875 http://dx.doi.org/10.1107/S1600536810041590 |
Sumario: | The asymmetric unit of the title compound, [CdCl(2)(C(8)H(6)N(2)O)(2)](n), consists of one molecule of the 3H-quinazolin-4-one ligand, one Cd(2+) cation, which is located on a twofold axis, and one chlorido ligand in a general position. The latter bridges metal cations, forming a one-dimensional polymer along the b axis. The Cd⋯Cd distance along the chain is 3.7309 (7) Å. The octahedral coordination around the metal is completed by two ligands in a trans axial geometry which coordinate through the N atom in 1 position. Moderately strong classical N—H⋯O hydrogen bonds around crystallographic inversion centers cross-link adjacent polymeric chains. |
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