catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido]

The asymmetric unit of the title compound, [CdCl(2)(C(8)H(6)N(2)O)(2)](n), consists of one mol­ecule of the 3H-quinazolin-4-one ligand, one Cd(2+) cation, which is located on a twofold axis, and one chlorido ligand in a general position. The latter bridges metal cations, forming a one-dimensional po...

Descripción completa

Detalles Bibliográficos
Autores principales: Turgunov, Kambarali, Englert, Ulli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009324/
https://www.ncbi.nlm.nih.gov/pubmed/21588875
http://dx.doi.org/10.1107/S1600536810041590
_version_ 1782194661032460288
author Turgunov, Kambarali
Englert, Ulli
author_facet Turgunov, Kambarali
Englert, Ulli
author_sort Turgunov, Kambarali
collection PubMed
description The asymmetric unit of the title compound, [CdCl(2)(C(8)H(6)N(2)O)(2)](n), consists of one mol­ecule of the 3H-quinazolin-4-one ligand, one Cd(2+) cation, which is located on a twofold axis, and one chlorido ligand in a general position. The latter bridges metal cations, forming a one-dimensional polymer along the b axis. The Cd⋯Cd distance along the chain is 3.7309 (7) Å. The octa­hedral coordination around the metal is completed by two ligands in a trans axial geometry which coordinate through the N atom in 1 position. Moderately strong classical N—H⋯O hydrogen bonds around crystallographic inversion centers cross-link adjacent polymeric chains.
format Text
id pubmed-3009324
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30093242010-12-30 catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido] Turgunov, Kambarali Englert, Ulli Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CdCl(2)(C(8)H(6)N(2)O)(2)](n), consists of one mol­ecule of the 3H-quinazolin-4-one ligand, one Cd(2+) cation, which is located on a twofold axis, and one chlorido ligand in a general position. The latter bridges metal cations, forming a one-dimensional polymer along the b axis. The Cd⋯Cd distance along the chain is 3.7309 (7) Å. The octa­hedral coordination around the metal is completed by two ligands in a trans axial geometry which coordinate through the N atom in 1 position. Moderately strong classical N—H⋯O hydrogen bonds around crystallographic inversion centers cross-link adjacent polymeric chains. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009324/ /pubmed/21588875 http://dx.doi.org/10.1107/S1600536810041590 Text en © Turgunov and Englert 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Turgunov, Kambarali
Englert, Ulli
catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido]
title catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido]
title_full catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido]
title_fullStr catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido]
title_full_unstemmed catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido]
title_short catena-Poly[[bis[quinazolin-4(3H)-one-κN (1)]cadmium(II)]-di-μ-chlorido]
title_sort catena-poly[[bis[quinazolin-4(3h)-one-κn (1)]cadmium(ii)]-di-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009324/
https://www.ncbi.nlm.nih.gov/pubmed/21588875
http://dx.doi.org/10.1107/S1600536810041590
work_keys_str_mv AT turgunovkambarali catenapolybisquinazolin43honekn1cadmiumiidimchlorido
AT englertulli catenapolybisquinazolin43honekn1cadmiumiidimchlorido

Ejemplares similares