Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) N,O,N′]iodidocadmium(II)}

In the centrosymmetric dinuclear title compound, [Cd(2)I(4)(C(12)H(12)N(2)O(2))(2)], two μ-I atoms bridge two Cd(II) atoms and each Cd(II) atom is also bonded to a terminal I atom and a hy­droxy-meth­oxy-bis­(2-pyrid­yl)methane ligand, which functions in an N,O,N′-tridentate mode, resulting in a dis...

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Detalles Bibliográficos
Autores principales: Esmhosseini, Majid, Safari, Nasser, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009326/
https://www.ncbi.nlm.nih.gov/pubmed/21588858
http://dx.doi.org/10.1107/S1600536810041681
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author Esmhosseini, Majid
Safari, Nasser
Amani, Vahid
author_facet Esmhosseini, Majid
Safari, Nasser
Amani, Vahid
author_sort Esmhosseini, Majid
collection PubMed
description In the centrosymmetric dinuclear title compound, [Cd(2)I(4)(C(12)H(12)N(2)O(2))(2)], two μ-I atoms bridge two Cd(II) atoms and each Cd(II) atom is also bonded to a terminal I atom and a hy­droxy-meth­oxy-bis­(2-pyrid­yl)methane ligand, which functions in an N,O,N′-tridentate mode, resulting in a distorted octa­hedral coordination environment. Inter­molecular O—H⋯I hydrogen bonds and π–π stacking inter­actions between the pyridine rings [centroid–centroid distance = 3.790 (2) Å] are present in the crystal structure.
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spelling pubmed-30093262010-12-30 Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) N,O,N′]iodidocadmium(II)} Esmhosseini, Majid Safari, Nasser Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Cd(2)I(4)(C(12)H(12)N(2)O(2))(2)], two μ-I atoms bridge two Cd(II) atoms and each Cd(II) atom is also bonded to a terminal I atom and a hy­droxy-meth­oxy-bis­(2-pyrid­yl)methane ligand, which functions in an N,O,N′-tridentate mode, resulting in a distorted octa­hedral coordination environment. Inter­molecular O—H⋯I hydrogen bonds and π–π stacking inter­actions between the pyridine rings [centroid–centroid distance = 3.790 (2) Å] are present in the crystal structure. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009326/ /pubmed/21588858 http://dx.doi.org/10.1107/S1600536810041681 Text en © Esmhosseini et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Esmhosseini, Majid
Safari, Nasser
Amani, Vahid
Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) N,O,N′]iodidocadmium(II)}
title Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) N,O,N′]iodidocadmium(II)}
title_full Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) N,O,N′]iodidocadmium(II)}
title_fullStr Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) N,O,N′]iodidocadmium(II)}
title_full_unstemmed Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) N,O,N′]iodidocadmium(II)}
title_short Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) N,O,N′]iodidocadmium(II)}
title_sort di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ(3) n,o,n′]iodidocadmium(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009326/
https://www.ncbi.nlm.nih.gov/pubmed/21588858
http://dx.doi.org/10.1107/S1600536810041681
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