N-(4-Bromo­phen­yl)urea

In the title compound, C(7)H(7)BrN(2)O, both the urea moiety [maximum deviation 0.003 (2) Å] and the benzene ring are essentially planar [maximum deviation 0.003 (2) Å] but are rotated with respect to each other by a dihedral angle of 47.8 (1)°. The crystal assembly is stabilized by N—H⋯O hydrogen b...

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Detalles Bibliográficos
Autores principales: Štěpnička, Petr, Císařová, Ivana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009331/
https://www.ncbi.nlm.nih.gov/pubmed/21589060
http://dx.doi.org/10.1107/S1600536810041735
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author Štěpnička, Petr
Císařová, Ivana
author_facet Štěpnička, Petr
Císařová, Ivana
author_sort Štěpnička, Petr
collection PubMed
description In the title compound, C(7)H(7)BrN(2)O, both the urea moiety [maximum deviation 0.003 (2) Å] and the benzene ring are essentially planar [maximum deviation 0.003 (2) Å] but are rotated with respect to each other by a dihedral angle of 47.8 (1)°. The crystal assembly is stabilized by N—H⋯O hydrogen bonds between all NH protons as conventional hydrogen bond donors and the C=O oxygen as a trifurcated hydrogen-bond acceptor. Both the overall mol­ecular geometry and the crystal packing of the title compound are very similar to those of N-phenyl­urea, which is underscored by a practically isostructural relationship between these two urea derivatives.
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spelling pubmed-30093312010-12-30 N-(4-Bromo­phen­yl)urea Štěpnička, Petr Císařová, Ivana Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(7)BrN(2)O, both the urea moiety [maximum deviation 0.003 (2) Å] and the benzene ring are essentially planar [maximum deviation 0.003 (2) Å] but are rotated with respect to each other by a dihedral angle of 47.8 (1)°. The crystal assembly is stabilized by N—H⋯O hydrogen bonds between all NH protons as conventional hydrogen bond donors and the C=O oxygen as a trifurcated hydrogen-bond acceptor. Both the overall mol­ecular geometry and the crystal packing of the title compound are very similar to those of N-phenyl­urea, which is underscored by a practically isostructural relationship between these two urea derivatives. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009331/ /pubmed/21589060 http://dx.doi.org/10.1107/S1600536810041735 Text en © Štěpnička and Císařová 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Štěpnička, Petr
Císařová, Ivana
N-(4-Bromo­phen­yl)urea
title N-(4-Bromo­phen­yl)urea
title_full N-(4-Bromo­phen­yl)urea
title_fullStr N-(4-Bromo­phen­yl)urea
title_full_unstemmed N-(4-Bromo­phen­yl)urea
title_short N-(4-Bromo­phen­yl)urea
title_sort n-(4-bromo­phen­yl)urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009331/
https://www.ncbi.nlm.nih.gov/pubmed/21589060
http://dx.doi.org/10.1107/S1600536810041735
work_keys_str_mv AT stepnickapetr n4bromophenylurea
AT cisarovaivana n4bromophenylurea

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