catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ(2)-iodido]

The solvothermal reaction of copper(I) iodide and 1,10-phenanthroline (phen) in ethanol yielded the title polymeric compound, [CuI(C(12)H(8)N(2))](n). The asymmmetric unit comprises one Cu(+) cation, one I(−) anion and one phen ligand. Each Cu(+) cation is in a distorted tetrahedral coordination by...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Yisheng, Chai, Wenxiang, Song, Li, Shu, Kangying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009332/
https://www.ncbi.nlm.nih.gov/pubmed/21588901
http://dx.doi.org/10.1107/S1600536810043205
_version_ 1782194662933528576
author Yang, Yisheng
Chai, Wenxiang
Song, Li
Shu, Kangying
author_facet Yang, Yisheng
Chai, Wenxiang
Song, Li
Shu, Kangying
author_sort Yang, Yisheng
collection PubMed
description The solvothermal reaction of copper(I) iodide and 1,10-phenanthroline (phen) in ethanol yielded the title polymeric compound, [CuI(C(12)H(8)N(2))](n). The asymmmetric unit comprises one Cu(+) cation, one I(−) anion and one phen ligand. Each Cu(+) cation is in a distorted tetrahedral coordination by two iodide anions and two N atoms from a bidentate chelating phen ligand. The Cu(+) cations are bridged through the iodide anions, leading to a zigzag chain structure extending parallel to [100]. There are π–π inter­actions among adjacent phen ligands of one chain [centroid–centroid distance = 3.693 (3) Å].
format Text
id pubmed-3009332
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30093322010-12-30 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ(2)-iodido] Yang, Yisheng Chai, Wenxiang Song, Li Shu, Kangying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The solvothermal reaction of copper(I) iodide and 1,10-phenanthroline (phen) in ethanol yielded the title polymeric compound, [CuI(C(12)H(8)N(2))](n). The asymmmetric unit comprises one Cu(+) cation, one I(−) anion and one phen ligand. Each Cu(+) cation is in a distorted tetrahedral coordination by two iodide anions and two N atoms from a bidentate chelating phen ligand. The Cu(+) cations are bridged through the iodide anions, leading to a zigzag chain structure extending parallel to [100]. There are π–π inter­actions among adjacent phen ligands of one chain [centroid–centroid distance = 3.693 (3) Å]. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009332/ /pubmed/21588901 http://dx.doi.org/10.1107/S1600536810043205 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Yisheng
Chai, Wenxiang
Song, Li
Shu, Kangying
catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ(2)-iodido]
title catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ(2)-iodido]
title_full catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ(2)-iodido]
title_fullStr catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ(2)-iodido]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ(2)-iodido]
title_short catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ(2)-iodido]
title_sort catena-poly[[(1,10-phenanthroline-κ(2) n,n′)copper(i)]-μ(2)-iodido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009332/
https://www.ncbi.nlm.nih.gov/pubmed/21588901
http://dx.doi.org/10.1107/S1600536810043205
work_keys_str_mv AT yangyisheng catenapoly110phenanthrolinek2nncopperim2iodido
AT chaiwenxiang catenapoly110phenanthrolinek2nncopperim2iodido
AT songli catenapoly110phenanthrolinek2nncopperim2iodido
AT shukangying catenapoly110phenanthrolinek2nncopperim2iodido

Ejemplares similares