9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through C—H⋯O, C—F⋯π and π–π inter­actions. These dimers are further linked by π–π inter­actions. The cations and anions are connected through C—H⋯O, C—F⋯π and S—O⋯π inter­actions....

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009336/
https://www.ncbi.nlm.nih.gov/pubmed/21588971
http://dx.doi.org/10.1107/S1600536810039231
Descripción
Sumario:In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through C—H⋯O, C—F⋯π and π–π inter­actions. These dimers are further linked by π–π inter­actions. The cations and anions are connected through C—H⋯O, C—F⋯π and S—O⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 74.1 (1)°. The carboxyl­ate group is twisted at an angle of 4.4 (1)° relative to the acridine skeleton. The mean planes of the adjacent acridine moieties are parallel or inclined at an angle of 55.4 (1)° in the crystal structure.

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