Cargando…
9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through C—H⋯O, C—F⋯π and π–π interactions. These dimers are further linked by π–π interactions. The cations and anions are connected through C—H⋯O, C—F⋯π and S—O⋯π interactions....
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009336/ https://www.ncbi.nlm.nih.gov/pubmed/21588971 http://dx.doi.org/10.1107/S1600536810039231 |
_version_ | 1782194664042921984 |
---|---|
author | Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy |
author_facet | Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy |
author_sort | Trzybiński, Damian |
collection | PubMed |
description | In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through C—H⋯O, C—F⋯π and π–π interactions. These dimers are further linked by π–π interactions. The cations and anions are connected through C—H⋯O, C—F⋯π and S—O⋯π interactions. The acridine and benzene ring systems are oriented at a dihedral angle of 74.1 (1)°. The carboxylate group is twisted at an angle of 4.4 (1)° relative to the acridine skeleton. The mean planes of the adjacent acridine moieties are parallel or inclined at an angle of 55.4 (1)° in the crystal structure. |
format | Text |
id | pubmed-3009336 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30093362010-12-30 9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through C—H⋯O, C—F⋯π and π–π interactions. These dimers are further linked by π–π interactions. The cations and anions are connected through C—H⋯O, C—F⋯π and S—O⋯π interactions. The acridine and benzene ring systems are oriented at a dihedral angle of 74.1 (1)°. The carboxylate group is twisted at an angle of 4.4 (1)° relative to the acridine skeleton. The mean planes of the adjacent acridine moieties are parallel or inclined at an angle of 55.4 (1)° in the crystal structure. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009336/ /pubmed/21588971 http://dx.doi.org/10.1107/S1600536810039231 Text en © Trzybiński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy 9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title | 9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_full | 9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_fullStr | 9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_full_unstemmed | 9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_short | 9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_sort | 9-(4-fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009336/ https://www.ncbi.nlm.nih.gov/pubmed/21588971 http://dx.doi.org/10.1107/S1600536810039231 |
work_keys_str_mv | AT trzybinskidamian 94fluorophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate AT krzyminskikarol 94fluorophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate AT błazejowskijerzy 94fluorophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate |