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9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through C—H⋯O, C—F⋯π and π–π inter­actions. These dimers are further linked by π–π inter­actions. The cations and anions are connected through C—H⋯O, C—F⋯π and S—O⋯π inter­actions....

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009336/
https://www.ncbi.nlm.nih.gov/pubmed/21588971
http://dx.doi.org/10.1107/S1600536810039231
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author Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through C—H⋯O, C—F⋯π and π–π inter­actions. These dimers are further linked by π–π inter­actions. The cations and anions are connected through C—H⋯O, C—F⋯π and S—O⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 74.1 (1)°. The carboxyl­ate group is twisted at an angle of 4.4 (1)° relative to the acridine skeleton. The mean planes of the adjacent acridine moieties are parallel or inclined at an angle of 55.4 (1)° in the crystal structure.
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spelling pubmed-30093362010-12-30 9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through C—H⋯O, C—F⋯π and π–π inter­actions. These dimers are further linked by π–π inter­actions. The cations and anions are connected through C—H⋯O, C—F⋯π and S—O⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 74.1 (1)°. The carboxyl­ate group is twisted at an angle of 4.4 (1)° relative to the acridine skeleton. The mean planes of the adjacent acridine moieties are parallel or inclined at an angle of 55.4 (1)° in the crystal structure. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009336/ /pubmed/21588971 http://dx.doi.org/10.1107/S1600536810039231 Text en © Trzybiński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title 9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full 9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_fullStr 9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_short 9-(4-Fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_sort 9-(4-fluoro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009336/
https://www.ncbi.nlm.nih.gov/pubmed/21588971
http://dx.doi.org/10.1107/S1600536810039231
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AT błazejowskijerzy 94fluorophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate