1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene

Following our continuing inter­est in developing new chiral phosphine-containing ferrocenyl ligands, we synthesized the title compound, [Fe(C(5)H(5))(C(26)H(24)OPS)], in which there are two nearly identical mol­ecules in the asymmetric unit. The conformation of the cyclo­penta­dienyl (Cp) rings in e...

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Detalles Bibliográficos
Autores principales: Daran, Jean-Claude, Audin, Catherine, Deydier, Eric, Manoury, Eric, Poli, Rinaldo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009340/
https://www.ncbi.nlm.nih.gov/pubmed/21588845
http://dx.doi.org/10.1107/S1600536810040791
Descripción
Sumario:Following our continuing inter­est in developing new chiral phosphine-containing ferrocenyl ligands, we synthesized the title compound, [Fe(C(5)H(5))(C(26)H(24)OPS)], in which there are two nearly identical mol­ecules in the asymmetric unit. The conformation of the cyclo­penta­dienyl (Cp) rings in each ferrocenyl group are inter­mediate between eclipsed and staggered, with twist angles of 16.6 (2) and 8.9 (2)°. The protecting S atom is located endo with respect to the substituted Cp ring. In the crystal, mol­ecules are connected through inter­molecular C—H⋯π inter­actions.

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