1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene

Following our continuing inter­est in developing new chiral phosphine-containing ferrocenyl ligands, we synthesized the title compound, [Fe(C(5)H(5))(C(26)H(24)OPS)], in which there are two nearly identical mol­ecules in the asymmetric unit. The conformation of the cyclo­penta­dienyl (Cp) rings in e...

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Autores principales: Daran, Jean-Claude, Audin, Catherine, Deydier, Eric, Manoury, Eric, Poli, Rinaldo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009340/
https://www.ncbi.nlm.nih.gov/pubmed/21588845
http://dx.doi.org/10.1107/S1600536810040791
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author Daran, Jean-Claude
Audin, Catherine
Deydier, Eric
Manoury, Eric
Poli, Rinaldo
author_facet Daran, Jean-Claude
Audin, Catherine
Deydier, Eric
Manoury, Eric
Poli, Rinaldo
author_sort Daran, Jean-Claude
collection PubMed
description Following our continuing inter­est in developing new chiral phosphine-containing ferrocenyl ligands, we synthesized the title compound, [Fe(C(5)H(5))(C(26)H(24)OPS)], in which there are two nearly identical mol­ecules in the asymmetric unit. The conformation of the cyclo­penta­dienyl (Cp) rings in each ferrocenyl group are inter­mediate between eclipsed and staggered, with twist angles of 16.6 (2) and 8.9 (2)°. The protecting S atom is located endo with respect to the substituted Cp ring. In the crystal, mol­ecules are connected through inter­molecular C—H⋯π inter­actions.
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spelling pubmed-30093402010-12-30 1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene Daran, Jean-Claude Audin, Catherine Deydier, Eric Manoury, Eric Poli, Rinaldo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Following our continuing inter­est in developing new chiral phosphine-containing ferrocenyl ligands, we synthesized the title compound, [Fe(C(5)H(5))(C(26)H(24)OPS)], in which there are two nearly identical mol­ecules in the asymmetric unit. The conformation of the cyclo­penta­dienyl (Cp) rings in each ferrocenyl group are inter­mediate between eclipsed and staggered, with twist angles of 16.6 (2) and 8.9 (2)°. The protecting S atom is located endo with respect to the substituted Cp ring. In the crystal, mol­ecules are connected through inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009340/ /pubmed/21588845 http://dx.doi.org/10.1107/S1600536810040791 Text en © Daran et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Daran, Jean-Claude
Audin, Catherine
Deydier, Eric
Manoury, Eric
Poli, Rinaldo
1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene
title 1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene
title_full 1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene
title_fullStr 1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene
title_full_unstemmed 1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene
title_short 1-(Diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene
title_sort 1-(diphenyl­phosphinothio­yl)-2-[(4-methyl­phen­yl)meth­oxy­meth­yl]ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009340/
https://www.ncbi.nlm.nih.gov/pubmed/21588845
http://dx.doi.org/10.1107/S1600536810040791
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