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Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′);κ(4) O (1):O (1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2) O (1),O (1′)](1,10-phenanthroline-κ(2) N,N′)erbium(III)}
In the dimeric centrosymmetric title complex, [Er(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Er(III) ion is nine-coordinated by five 2-(3,4-dimethoxylphenyl)acetic acid (DMPA) ligands via seven O atoms and two N atoms from a bis-chelating 1,10-phenanthroline (phen) ligand in a distorted tricap...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009341/ https://www.ncbi.nlm.nih.gov/pubmed/21588841 http://dx.doi.org/10.1107/S1600536810040298 |
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| author | Liu, Jia-Lu Li, Hua-Qiong Zhao, Guo-Liang |
| author_facet | Liu, Jia-Lu Li, Hua-Qiong Zhao, Guo-Liang |
| author_sort | Liu, Jia-Lu |
| collection | PubMed |
| description | In the dimeric centrosymmetric title complex, [Er(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Er(III) ion is nine-coordinated by five 2-(3,4-dimethoxylphenyl)acetic acid (DMPA) ligands via seven O atoms and two N atoms from a bis-chelating 1,10-phenanthroline (phen) ligand in a distorted tricapped trigonal-prismatic geometry. The DMPA ligands are coordinated to the Er(III) ion in bis-chelate, bridging and bridging tridentate modes. Relatively weak intramolecular C—H⋯O interactions reinforce the stability of the molecular structure. Intermolecular C—H⋯O interactions are also observed. |
| format | Text |
| id | pubmed-3009341 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30093412010-12-30 Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′);κ(4) O (1):O (1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2) O (1),O (1′)](1,10-phenanthroline-κ(2) N,N′)erbium(III)} Liu, Jia-Lu Li, Hua-Qiong Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dimeric centrosymmetric title complex, [Er(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Er(III) ion is nine-coordinated by five 2-(3,4-dimethoxylphenyl)acetic acid (DMPA) ligands via seven O atoms and two N atoms from a bis-chelating 1,10-phenanthroline (phen) ligand in a distorted tricapped trigonal-prismatic geometry. The DMPA ligands are coordinated to the Er(III) ion in bis-chelate, bridging and bridging tridentate modes. Relatively weak intramolecular C—H⋯O interactions reinforce the stability of the molecular structure. Intermolecular C—H⋯O interactions are also observed. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009341/ /pubmed/21588841 http://dx.doi.org/10.1107/S1600536810040298 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jia-Lu Li, Hua-Qiong Zhao, Guo-Liang Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′);κ(4) O (1):O (1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2) O (1),O (1′)](1,10-phenanthroline-κ(2) N,N′)erbium(III)} |
| title | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′);κ(4)
O
(1):O
(1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O
(1),O
(1′)](1,10-phenanthroline-κ(2)
N,N′)erbium(III)} |
| title_full | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′);κ(4)
O
(1):O
(1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O
(1),O
(1′)](1,10-phenanthroline-κ(2)
N,N′)erbium(III)} |
| title_fullStr | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′);κ(4)
O
(1):O
(1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O
(1),O
(1′)](1,10-phenanthroline-κ(2)
N,N′)erbium(III)} |
| title_full_unstemmed | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′);κ(4)
O
(1):O
(1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O
(1),O
(1′)](1,10-phenanthroline-κ(2)
N,N′)erbium(III)} |
| title_short | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′);κ(4)
O
(1):O
(1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O
(1),O
(1′)](1,10-phenanthroline-κ(2)
N,N′)erbium(III)} |
| title_sort | tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(3)
o
(1),o
(1′):o
(1);κ(3)
o
(1):o
(1),o
(1′);κ(4)
o
(1):o
(1′)-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
o
(1),o
(1′)](1,10-phenanthroline-κ(2)
n,n′)erbium(iii)} |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009341/ https://www.ncbi.nlm.nih.gov/pubmed/21588841 http://dx.doi.org/10.1107/S1600536810040298 |
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