(Z)-1-Phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one

The reaction of 3-C(5)H(4)NCH(2)NH(2) and C(6)H(5)COCH(2)COCH(3) affords the title compound, C(16)H(16)N(2)O. The O=C—C=C—N portion is essentially planar [maximum deviation = 0.046 (2) Å] and is aligned at dihedral angles of 22.6 (1) and 78.9 (1)° to the phenyl and pyridyl rings, respectively. The N...

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Detalles Bibliográficos
Autores principales: Shi, Yao-Cheng, Zhu, Bei-Bei, Zhang, Su-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009348/
https://www.ncbi.nlm.nih.gov/pubmed/21589039
http://dx.doi.org/10.1107/S1600536810041127
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author Shi, Yao-Cheng
Zhu, Bei-Bei
Zhang, Su-Hua
author_facet Shi, Yao-Cheng
Zhu, Bei-Bei
Zhang, Su-Hua
author_sort Shi, Yao-Cheng
collection PubMed
description The reaction of 3-C(5)H(4)NCH(2)NH(2) and C(6)H(5)COCH(2)COCH(3) affords the title compound, C(16)H(16)N(2)O. The O=C—C=C—N portion is essentially planar [maximum deviation = 0.046 (2) Å] and is aligned at dihedral angles of 22.6 (1) and 78.9 (1)° to the phenyl and pyridyl rings, respectively. The N—H and O=C groups are linked by an intra­molecular hydrogen bond. In the crystal, C—H⋯O hydrogen bonds and C—H⋯π inter­actions occur.
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spelling pubmed-30093482010-12-30 (Z)-1-Phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one Shi, Yao-Cheng Zhu, Bei-Bei Zhang, Su-Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of 3-C(5)H(4)NCH(2)NH(2) and C(6)H(5)COCH(2)COCH(3) affords the title compound, C(16)H(16)N(2)O. The O=C—C=C—N portion is essentially planar [maximum deviation = 0.046 (2) Å] and is aligned at dihedral angles of 22.6 (1) and 78.9 (1)° to the phenyl and pyridyl rings, respectively. The N—H and O=C groups are linked by an intra­molecular hydrogen bond. In the crystal, C—H⋯O hydrogen bonds and C—H⋯π inter­actions occur. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009348/ /pubmed/21589039 http://dx.doi.org/10.1107/S1600536810041127 Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shi, Yao-Cheng
Zhu, Bei-Bei
Zhang, Su-Hua
(Z)-1-Phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one
title (Z)-1-Phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one
title_full (Z)-1-Phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one
title_fullStr (Z)-1-Phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one
title_full_unstemmed (Z)-1-Phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one
title_short (Z)-1-Phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one
title_sort (z)-1-phenyl-3-(3-pyridyl­meth­ylamino)­but-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009348/
https://www.ncbi.nlm.nih.gov/pubmed/21589039
http://dx.doi.org/10.1107/S1600536810041127
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