Cargando…

Redetermination of 3-methyl­isoquinoline at 150 K

The structure of the title compound, C(19)H(9)O, has been redetermined at 150 K. The redetermination is of significantly higher precision than a previous room-temperature structure [Ribar et al. (1974 ▶). Cryst. Struct. Commun. 3, 323–325]. The C—N bond lengths for this redetermination are much clos...

Descripción completa

Detalles Bibliográficos
Autor principal: Bond, Andrew D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009354/
https://www.ncbi.nlm.nih.gov/pubmed/21588970
http://dx.doi.org/10.1107/S1600536810039838
Descripción
Sumario:The structure of the title compound, C(19)H(9)O, has been redetermined at 150 K. The redetermination is of significantly higher precision than a previous room-temperature structure [Ribar et al. (1974 ▶). Cryst. Struct. Commun. 3, 323–325]. The C—N bond lengths for this redetermination are much closer to those observed in comparable structures, and the orientation of the methyl group with respect to the isoquinoline plane is clarified. Inter­molecular weak C—H⋯N contacts are present in the crystal.