(2-Hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone

In the title compound, C(19)H(16)O(3), an intra­molecular O—H⋯O=C hydrogen bond is formed between the hy­droxy and carbonyl groups on the naphthalene ring system, resulting in an S(6) ring. The angles between the C=O bond vector and the least-squares planes of the naphthalene ring system and the ben...

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Detalles Bibliográficos
Autores principales: Nagasawa, Atsushi, Mitsui, Ryosuke, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009359/
https://www.ncbi.nlm.nih.gov/pubmed/21589009
http://dx.doi.org/10.1107/S1600536810040614
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author Nagasawa, Atsushi
Mitsui, Ryosuke
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Nagasawa, Atsushi
Mitsui, Ryosuke
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Nagasawa, Atsushi
collection PubMed
description In the title compound, C(19)H(16)O(3), an intra­molecular O—H⋯O=C hydrogen bond is formed between the hy­droxy and carbonyl groups on the naphthalene ring system, resulting in an S(6) ring. The angles between the C=O bond vector and the least-squares planes of the naphthalene ring system and the benzene ring are 27.63 (6) and 47.99 (7)°, respectively. The dihedral angle between the latter planes is 61.39 (5)°. In the crystal, two mol­ecules are connected by pairs of inter­molecular O—H⋯O=C hydrogen bonds, forming centrosymmetric dimers with an R (2) (2)(4) graph-set motif. The mol­ecular packing features C—H⋯π interactions.
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spelling pubmed-30093592010-12-30 (2-Hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone Nagasawa, Atsushi Mitsui, Ryosuke Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(16)O(3), an intra­molecular O—H⋯O=C hydrogen bond is formed between the hy­droxy and carbonyl groups on the naphthalene ring system, resulting in an S(6) ring. The angles between the C=O bond vector and the least-squares planes of the naphthalene ring system and the benzene ring are 27.63 (6) and 47.99 (7)°, respectively. The dihedral angle between the latter planes is 61.39 (5)°. In the crystal, two mol­ecules are connected by pairs of inter­molecular O—H⋯O=C hydrogen bonds, forming centrosymmetric dimers with an R (2) (2)(4) graph-set motif. The mol­ecular packing features C—H⋯π interactions. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009359/ /pubmed/21589009 http://dx.doi.org/10.1107/S1600536810040614 Text en © Nagasawa et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nagasawa, Atsushi
Mitsui, Ryosuke
Okamoto, Akiko
Yonezawa, Noriyuki
(2-Hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone
title (2-Hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone
title_full (2-Hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone
title_fullStr (2-Hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone
title_full_unstemmed (2-Hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone
title_short (2-Hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone
title_sort (2-hy­droxy-7-meth­oxy­naphthalen-1-yl)(4-methyl­phen­yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009359/
https://www.ncbi.nlm.nih.gov/pubmed/21589009
http://dx.doi.org/10.1107/S1600536810040614
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AT mitsuiryosuke 2hydroxy7methoxynaphthalen1yl4methylphenylmethanone
AT okamotoakiko 2hydroxy7methoxynaphthalen1yl4methylphenylmethanone
AT yonezawanoriyuki 2hydroxy7methoxynaphthalen1yl4methylphenylmethanone

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