4-Chloro-2-(6-nitro-1H-benzimidazol-2-yl)phenol N,N-dimethyl­form­amide solvate

In the title compound, C(13)H(8)ClN(3)O(3)·C(3)H(7)NO, the benzimidazole and benzene rings make a dihedral angle of 0.63 (11)°. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. The solvent mol­ecule is hydrogen-bonded to the benzimidazole mol­ecule by inter­molecular N—H⋯O and C—...

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Autores principales: Farag, Abeer Mohamed, Teoh, Siang Guan, Osman, Hasnah, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009370/
https://www.ncbi.nlm.nih.gov/pubmed/21589045
http://dx.doi.org/10.1107/S1600536810041243
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author Farag, Abeer Mohamed
Teoh, Siang Guan
Osman, Hasnah
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Farag, Abeer Mohamed
Teoh, Siang Guan
Osman, Hasnah
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Farag, Abeer Mohamed
collection PubMed
description In the title compound, C(13)H(8)ClN(3)O(3)·C(3)H(7)NO, the benzimidazole and benzene rings make a dihedral angle of 0.63 (11)°. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. The solvent mol­ecule is hydrogen-bonded to the benzimidazole mol­ecule by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, generating an R (1) (2)(7) ring motif. In the crystal, the mol­ecules are arranged into parallel layers perpendicular to the c axis and stabilized by weak π–π inter­actions [centroid–centroid distances in the range 3.4036 (18)–3.5878 (16) Å].
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spelling pubmed-30093702010-12-30 4-Chloro-2-(6-nitro-1H-benzimidazol-2-yl)phenol N,N-dimethyl­form­amide solvate Farag, Abeer Mohamed Teoh, Siang Guan Osman, Hasnah Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(8)ClN(3)O(3)·C(3)H(7)NO, the benzimidazole and benzene rings make a dihedral angle of 0.63 (11)°. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. The solvent mol­ecule is hydrogen-bonded to the benzimidazole mol­ecule by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, generating an R (1) (2)(7) ring motif. In the crystal, the mol­ecules are arranged into parallel layers perpendicular to the c axis and stabilized by weak π–π inter­actions [centroid–centroid distances in the range 3.4036 (18)–3.5878 (16) Å]. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009370/ /pubmed/21589045 http://dx.doi.org/10.1107/S1600536810041243 Text en © Farag et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Farag, Abeer Mohamed
Teoh, Siang Guan
Osman, Hasnah
Yeap, Chin Sing
Fun, Hoong-Kun
4-Chloro-2-(6-nitro-1H-benzimidazol-2-yl)phenol N,N-dimethyl­form­amide solvate
title 4-Chloro-2-(6-nitro-1H-benzimidazol-2-yl)phenol N,N-dimethyl­form­amide solvate
title_full 4-Chloro-2-(6-nitro-1H-benzimidazol-2-yl)phenol N,N-dimethyl­form­amide solvate
title_fullStr 4-Chloro-2-(6-nitro-1H-benzimidazol-2-yl)phenol N,N-dimethyl­form­amide solvate
title_full_unstemmed 4-Chloro-2-(6-nitro-1H-benzimidazol-2-yl)phenol N,N-dimethyl­form­amide solvate
title_short 4-Chloro-2-(6-nitro-1H-benzimidazol-2-yl)phenol N,N-dimethyl­form­amide solvate
title_sort 4-chloro-2-(6-nitro-1h-benzimidazol-2-yl)phenol n,n-dimethyl­form­amide solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009370/
https://www.ncbi.nlm.nih.gov/pubmed/21589045
http://dx.doi.org/10.1107/S1600536810041243
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