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Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate
The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris(3,5-di-tert-butylsalicylidenatoamino)triethylamine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the ce...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009372/ https://www.ncbi.nlm.nih.gov/pubmed/21588823 http://dx.doi.org/10.1107/S1600536810039565 |
Sumario: | The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris(3,5-di-tert-butylsalicylidenatoamino)triethylamine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce—N(imine) distance of 2.860 (2) Å and an average C—N(amine) distance of 2.619 Å within a distorted monocapped octahedral coordination. |
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