Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate

The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris­(3,5-di-tert-butyl­salicyl­ide­natoamino)­triethyl­amine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the ce...

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Detalles Bibliográficos
Autores principales: Dröse, Peter, Hrib, Cristian G., Edelmann, Frank T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009372/
https://www.ncbi.nlm.nih.gov/pubmed/21588823
http://dx.doi.org/10.1107/S1600536810039565
Descripción
Sumario:The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris­(3,5-di-tert-butyl­salicyl­ide­natoamino)­triethyl­amine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce—N(imine) distance of 2.860 (2) Å and an average C—N(amine) distance of 2.619 Å within a distorted monocapped octahedral coordination.

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