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Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate
The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris(3,5-di-tert-butylsalicylidenatoamino)triethylamine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the ce...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009372/ https://www.ncbi.nlm.nih.gov/pubmed/21588823 http://dx.doi.org/10.1107/S1600536810039565 |
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author | Dröse, Peter Hrib, Cristian G. Edelmann, Frank T. |
author_facet | Dröse, Peter Hrib, Cristian G. Edelmann, Frank T. |
author_sort | Dröse, Peter |
collection | PubMed |
description | The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris(3,5-di-tert-butylsalicylidenatoamino)triethylamine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce—N(imine) distance of 2.860 (2) Å and an average C—N(amine) distance of 2.619 Å within a distorted monocapped octahedral coordination. |
format | Text |
id | pubmed-3009372 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30093722010-12-30 Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate Dröse, Peter Hrib, Cristian G. Edelmann, Frank T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris(3,5-di-tert-butylsalicylidenatoamino)triethylamine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce—N(imine) distance of 2.860 (2) Å and an average C—N(amine) distance of 2.619 Å within a distorted monocapped octahedral coordination. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009372/ /pubmed/21588823 http://dx.doi.org/10.1107/S1600536810039565 Text en © Dröse et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dröse, Peter Hrib, Cristian G. Edelmann, Frank T. Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate |
title | Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate |
title_full | Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate |
title_fullStr | Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate |
title_full_unstemmed | Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate |
title_short | Bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate |
title_sort | bis({tris[2-(3,5-di-tert-butyl-2-oxidobenzylideneamino)ethyl]amine}cerium(iii)) diethyl ether solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009372/ https://www.ncbi.nlm.nih.gov/pubmed/21588823 http://dx.doi.org/10.1107/S1600536810039565 |
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