Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate

The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris­(3,5-di-tert-butyl­salicyl­ide­natoamino)­triethyl­amine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the ce...

Descripción completa

Detalles Bibliográficos
Autores principales: Dröse, Peter, Hrib, Cristian G., Edelmann, Frank T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009372/
https://www.ncbi.nlm.nih.gov/pubmed/21588823
http://dx.doi.org/10.1107/S1600536810039565
_version_ 1782194672598253568
author Dröse, Peter
Hrib, Cristian G.
Edelmann, Frank T.
author_facet Dröse, Peter
Hrib, Cristian G.
Edelmann, Frank T.
author_sort Dröse, Peter
collection PubMed
description The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris­(3,5-di-tert-butyl­salicyl­ide­natoamino)­triethyl­amine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce—N(imine) distance of 2.860 (2) Å and an average C—N(amine) distance of 2.619 Å within a distorted monocapped octahedral coordination.
format Text
id pubmed-3009372
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30093722010-12-30 Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate Dröse, Peter Hrib, Cristian G. Edelmann, Frank T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N′,N′′-tris­(3,5-di-tert-butyl­salicyl­ide­natoamino)­triethyl­amine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce—N(imine) distance of 2.860 (2) Å and an average C—N(amine) distance of 2.619 Å within a distorted monocapped octahedral coordination. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009372/ /pubmed/21588823 http://dx.doi.org/10.1107/S1600536810039565 Text en © Dröse et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dröse, Peter
Hrib, Cristian G.
Edelmann, Frank T.
Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate
title Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate
title_full Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate
title_fullStr Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate
title_full_unstemmed Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate
title_short Bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(III)) diethyl ether solvate
title_sort bis({tris[2-(3,5-di-tert-butyl-2-oxido­benzylideneamino)ethyl]amine}cerium(iii)) diethyl ether solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009372/
https://www.ncbi.nlm.nih.gov/pubmed/21588823
http://dx.doi.org/10.1107/S1600536810039565
work_keys_str_mv AT drosepeter bistris235ditertbutyl2oxidobenzylideneaminoethylamineceriumiiidiethylethersolvate
AT hribcristiang bistris235ditertbutyl2oxidobenzylideneaminoethylamineceriumiiidiethylethersolvate
AT edelmannfrankt bistris235ditertbutyl2oxidobenzylideneaminoethylamineceriumiiidiethylethersolvate

Ejemplares similares