2-Cyano­quinolin-1-ium nitrate

A proton is transferred from the nitric acid to the N atom of 2-cyano­quinoline during crystallization, resulting in the formation of the title salt, C(10)H(7)N(2) (+)·NO(3) (−). The quinolinium ring system is approximately planar, with a maximum deviation of 0.013 (3) Å. In the crystal, a very asym...

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Detalles Bibliográficos
Autores principales: Loh, Wan-Sin, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009375/
https://www.ncbi.nlm.nih.gov/pubmed/21588937
http://dx.doi.org/10.1107/S1600536810039243
Descripción
Sumario:A proton is transferred from the nitric acid to the N atom of 2-cyano­quinoline during crystallization, resulting in the formation of the title salt, C(10)H(7)N(2) (+)·NO(3) (−). The quinolinium ring system is approximately planar, with a maximum deviation of 0.013 (3) Å. In the crystal, a very asymmetric bifurcated N—H⋯(O,O) hydrogen bond to two O atoms of an adjacent nitrate anion occurs, generating an R (2) (1)(4) ring motif. C—H⋯O hydrogen bonds link the ions into sheets stacking along the a axis.

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