2-Cyano­quinolin-1-ium nitrate

A proton is transferred from the nitric acid to the N atom of 2-cyano­quinoline during crystallization, resulting in the formation of the title salt, C(10)H(7)N(2) (+)·NO(3) (−). The quinolinium ring system is approximately planar, with a maximum deviation of 0.013 (3) Å. In the crystal, a very asym...

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Detalles Bibliográficos
Autores principales: Loh, Wan-Sin, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009375/
https://www.ncbi.nlm.nih.gov/pubmed/21588937
http://dx.doi.org/10.1107/S1600536810039243
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author Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Loh, Wan-Sin
collection PubMed
description A proton is transferred from the nitric acid to the N atom of 2-cyano­quinoline during crystallization, resulting in the formation of the title salt, C(10)H(7)N(2) (+)·NO(3) (−). The quinolinium ring system is approximately planar, with a maximum deviation of 0.013 (3) Å. In the crystal, a very asymmetric bifurcated N—H⋯(O,O) hydrogen bond to two O atoms of an adjacent nitrate anion occurs, generating an R (2) (1)(4) ring motif. C—H⋯O hydrogen bonds link the ions into sheets stacking along the a axis.
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spelling pubmed-30093752010-12-30 2-Cyano­quinolin-1-ium nitrate Loh, Wan-Sin Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers A proton is transferred from the nitric acid to the N atom of 2-cyano­quinoline during crystallization, resulting in the formation of the title salt, C(10)H(7)N(2) (+)·NO(3) (−). The quinolinium ring system is approximately planar, with a maximum deviation of 0.013 (3) Å. In the crystal, a very asymmetric bifurcated N—H⋯(O,O) hydrogen bond to two O atoms of an adjacent nitrate anion occurs, generating an R (2) (1)(4) ring motif. C—H⋯O hydrogen bonds link the ions into sheets stacking along the a axis. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009375/ /pubmed/21588937 http://dx.doi.org/10.1107/S1600536810039243 Text en © Loh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Cyano­quinolin-1-ium nitrate
title 2-Cyano­quinolin-1-ium nitrate
title_full 2-Cyano­quinolin-1-ium nitrate
title_fullStr 2-Cyano­quinolin-1-ium nitrate
title_full_unstemmed 2-Cyano­quinolin-1-ium nitrate
title_short 2-Cyano­quinolin-1-ium nitrate
title_sort 2-cyano­quinolin-1-ium nitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009375/
https://www.ncbi.nlm.nih.gov/pubmed/21588937
http://dx.doi.org/10.1107/S1600536810039243
work_keys_str_mv AT lohwansin 2cyanoquinolin1iumnitrate
AT hemamalinimadhukar 2cyanoquinolin1iumnitrate
AT funhoongkun 2cyanoquinolin1iumnitrate

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