2,2′-[p-Phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate

The cation of the title salt, C(18)H(20)N(4) (2+)·2HSO(4) (−)·2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenyl­ene ring. Within the hydrogensulfate ion, the S—O(H) bond is the longest of the S—O bonds. The dihedral angle between the central and terminal...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Qi, Xiao-Juan, Kong, Li-Li, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011373/
https://www.ncbi.nlm.nih.gov/pubmed/21589579
http://dx.doi.org/10.1107/S1600536810047999
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author Gao, Shan
Qi, Xiao-Juan
Kong, Li-Li
Ng, Seik Weng
author_facet Gao, Shan
Qi, Xiao-Juan
Kong, Li-Li
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description The cation of the title salt, C(18)H(20)N(4) (2+)·2HSO(4) (−)·2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenyl­ene ring. Within the hydrogensulfate ion, the S—O(H) bond is the longest of the S—O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)°. In the crystal, the cation, anion and water mol­ecule inter­act by O—H⋯O and N—H⋯O hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-30113732010-12-30 2,2′-[p-Phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate Gao, Shan Qi, Xiao-Juan Kong, Li-Li Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The cation of the title salt, C(18)H(20)N(4) (2+)·2HSO(4) (−)·2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenyl­ene ring. Within the hydrogensulfate ion, the S—O(H) bond is the longest of the S—O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)°. In the crystal, the cation, anion and water mol­ecule inter­act by O—H⋯O and N—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011373/ /pubmed/21589579 http://dx.doi.org/10.1107/S1600536810047999 Text en © Gao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Shan
Qi, Xiao-Juan
Kong, Li-Li
Ng, Seik Weng
2,2′-[p-Phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate
title 2,2′-[p-Phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate
title_full 2,2′-[p-Phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate
title_fullStr 2,2′-[p-Phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate
title_full_unstemmed 2,2′-[p-Phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate
title_short 2,2′-[p-Phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate
title_sort 2,2′-[p-phenyl­enebis(methyl­idene­aza­ne­di­yl)]dipyridinium bis­(hydrogensulfate) dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011373/
https://www.ncbi.nlm.nih.gov/pubmed/21589579
http://dx.doi.org/10.1107/S1600536810047999
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AT konglili 22pphenylenebismethylideneazanediyldipyridiniumbishydrogensulfatedihydrate
AT ngseikweng 22pphenylenebismethylideneazanediyldipyridiniumbishydrogensulfatedihydrate

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