trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II)

The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl­benzaldehyde­amine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(...

Descripción completa

Detalles Bibliográficos
Autores principales: Cao, Ruixia, Sun, Hongjian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011379/
https://www.ncbi.nlm.nih.gov/pubmed/21589273
http://dx.doi.org/10.1107/S1600536810046234
Descripción
Sumario:The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl­benzaldehyde­amine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(II) atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions.

Ejemplares similares