trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II)

The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl­benzaldehyde­amine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(...

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Detalles Bibliográficos
Autores principales: Cao, Ruixia, Sun, Hongjian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011379/
https://www.ncbi.nlm.nih.gov/pubmed/21589273
http://dx.doi.org/10.1107/S1600536810046234
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author Cao, Ruixia
Sun, Hongjian
author_facet Cao, Ruixia
Sun, Hongjian
author_sort Cao, Ruixia
collection PubMed
description The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl­benzaldehyde­amine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(II) atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions.
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spelling pubmed-30113792010-12-30 trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II) Cao, Ruixia Sun, Hongjian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl­benzaldehyde­amine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(II) atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011379/ /pubmed/21589273 http://dx.doi.org/10.1107/S1600536810046234 Text en © Cao and Sun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cao, Ruixia
Sun, Hongjian
trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II)
title trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II)
title_full trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II)
title_fullStr trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II)
title_full_unstemmed trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II)
title_short trans-Chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) C (1),N}bis­(trimethyl­phosphane)nickel(II)
title_sort trans-chlorido{3-chloro-2-[(1-naphth­yl)imino­meth­yl]phenyl-κ(2) c (1),n}bis­(trimethyl­phosphane)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011379/
https://www.ncbi.nlm.nih.gov/pubmed/21589273
http://dx.doi.org/10.1107/S1600536810046234
work_keys_str_mv AT caoruixia transchlorido3chloro21naphthyliminomethylphenylk2c1nbistrimethylphosphanenickelii
AT sunhongjian transchlorido3chloro21naphthyliminomethylphenylk2c1nbistrimethylphosphanenickelii

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