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Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
In the title compound, [Co(C(13)H(9)ClN(3)O)(2)]NO(3)·1.5H(2)O, the central Co(3+) atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octahedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011380/ https://www.ncbi.nlm.nih.gov/pubmed/21589256 http://dx.doi.org/10.1107/S160053681004612X |
Sumario: | In the title compound, [Co(C(13)H(9)ClN(3)O)(2)]NO(3)·1.5H(2)O, the central Co(3+) atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octahedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water molecules, and the nitrate anion via classical intermolecular O—H⋯O and O—H⋯N hydrogen bonds and weak C—H⋯O contacts. |
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