Bis[4-chloro-N′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate

In the title compound, [Co(C(13)H(9)ClN(3)O)(2)]NO(3)·1.5H(2)O, the central Co(3+) atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octa­hedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully...

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Detalles Bibliográficos
Autores principales: Wu, Dayu, Zhao, Yan, Ye, Hui, Wu, Genhua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011380/
https://www.ncbi.nlm.nih.gov/pubmed/21589256
http://dx.doi.org/10.1107/S160053681004612X
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author Wu, Dayu
Zhao, Yan
Ye, Hui
Wu, Genhua
author_facet Wu, Dayu
Zhao, Yan
Ye, Hui
Wu, Genhua
author_sort Wu, Dayu
collection PubMed
description In the title compound, [Co(C(13)H(9)ClN(3)O)(2)]NO(3)·1.5H(2)O, the central Co(3+) atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octa­hedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water mol­ecules, and the nitrate anion via classical inter­molecular O—H⋯O and O—H⋯N hydrogen bonds and weak C—H⋯O contacts.
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spelling pubmed-30113802010-12-30 Bis[4-chloro-N′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate Wu, Dayu Zhao, Yan Ye, Hui Wu, Genhua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(13)H(9)ClN(3)O)(2)]NO(3)·1.5H(2)O, the central Co(3+) atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octa­hedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water mol­ecules, and the nitrate anion via classical inter­molecular O—H⋯O and O—H⋯N hydrogen bonds and weak C—H⋯O contacts. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011380/ /pubmed/21589256 http://dx.doi.org/10.1107/S160053681004612X Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Dayu
Zhao, Yan
Ye, Hui
Wu, Genhua
Bis[4-chloro-N′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title Bis[4-chloro-N′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_full Bis[4-chloro-N′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_fullStr Bis[4-chloro-N′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_full_unstemmed Bis[4-chloro-N′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_short Bis[4-chloro-N′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_sort bis[4-chloro-n′-(2-pyridyl­methyl­idene)benzohydrazidato]cobalt(iii) nitrate sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011380/
https://www.ncbi.nlm.nih.gov/pubmed/21589256
http://dx.doi.org/10.1107/S160053681004612X
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