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(E)-3-(Anthracen-9-yl)-1-(2-bromo­phen­yl)prop-2-en-1-one

The mol­ecule of the title chalcone, C(23)H(15)BrO, is not planar and exists in the E configuration with respect to the central C=C bond. The dihedral angle between the benzene and anthracene rings is 83.58 (6)°. The prop-2-en-1-one bridge makes dihedral angles of 63.00 (7) and 42.62 (16)° with the...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kobkeatthawin, Thawanrat, Joothamongkhon, Jaruwan, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011387/
https://www.ncbi.nlm.nih.gov/pubmed/21589590
http://dx.doi.org/10.1107/S1600536810048476
Descripción
Sumario:The mol­ecule of the title chalcone, C(23)H(15)BrO, is not planar and exists in the E configuration with respect to the central C=C bond. The dihedral angle between the benzene and anthracene rings is 83.58 (6)°. The prop-2-en-1-one bridge makes dihedral angles of 63.00 (7) and 42.62 (16)° with the benzene and anthracene rings, respectively. In the crystal, mol­ecules are linked into dimers by weak C—H⋯O inter­actions. These dimers are arranged parallel to the bc plane and are further stacked along the a axis by π–π inter­actions with a centroid–centroid distance of 3.7561 (9) Å. The crystal structure is further stabilized by C—H⋯π inter­actions.