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(E)-3-(Anthracen-9-yl)-1-(2-bromophenyl)prop-2-en-1-one
The molecule of the title chalcone, C(23)H(15)BrO, is not planar and exists in the E configuration with respect to the central C=C bond. The dihedral angle between the benzene and anthracene rings is 83.58 (6)°. The prop-2-en-1-one bridge makes dihedral angles of 63.00 (7) and 42.62 (16)° with the...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011387/ https://www.ncbi.nlm.nih.gov/pubmed/21589590 http://dx.doi.org/10.1107/S1600536810048476 |
Sumario: | The molecule of the title chalcone, C(23)H(15)BrO, is not planar and exists in the E configuration with respect to the central C=C bond. The dihedral angle between the benzene and anthracene rings is 83.58 (6)°. The prop-2-en-1-one bridge makes dihedral angles of 63.00 (7) and 42.62 (16)° with the benzene and anthracene rings, respectively. In the crystal, molecules are linked into dimers by weak C—H⋯O interactions. These dimers are arranged parallel to the bc plane and are further stacked along the a axis by π–π interactions with a centroid–centroid distance of 3.7561 (9) Å. The crystal structure is further stabilized by C—H⋯π interactions. |
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