Tetra­aqua­diazido­cobalt(II) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium

The asymmetric unit of the title compound, [Co(N(3))(2)(H(2)O)(4)]·C(14)H(12)N(2)O(4), comprises half of the cobalt(II) complex mol­ecule and a half of the 3,3′-dicarboxyl­ato-1,1′-ethyl­enedipyridinium mol­ecule. The Co(II) atom is located on an inversion centre and hence the complex mol­ecule adop...

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Detalles Bibliográficos
Autores principales: Wen, Yan-Qing, Tian, Chun-Yan, Gao, En-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011402/
https://www.ncbi.nlm.nih.gov/pubmed/21589255
http://dx.doi.org/10.1107/S1600536810046143
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author Wen, Yan-Qing
Tian, Chun-Yan
Gao, En-Qing
author_facet Wen, Yan-Qing
Tian, Chun-Yan
Gao, En-Qing
author_sort Wen, Yan-Qing
collection PubMed
description The asymmetric unit of the title compound, [Co(N(3))(2)(H(2)O)(4)]·C(14)H(12)N(2)O(4), comprises half of the cobalt(II) complex mol­ecule and a half of the 3,3′-dicarboxyl­ato-1,1′-ethyl­enedipyridinium mol­ecule. The Co(II) atom is located on an inversion centre and hence the complex mol­ecule adopts a centrosymmetric trans-octa­hedral geometry. The zwitterionic organic mol­ecule is also centrosymmetric with the centre of the C—C bond of the ethyl­ene moiety coinciding with an inversion centre. The adduct of metal complex and organic mol­ecule is associated into a three-dimenional network through O—H⋯O hydrogen bonds.
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spelling pubmed-30114022010-12-30 Tetra­aqua­diazido­cobalt(II) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium Wen, Yan-Qing Tian, Chun-Yan Gao, En-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(N(3))(2)(H(2)O)(4)]·C(14)H(12)N(2)O(4), comprises half of the cobalt(II) complex mol­ecule and a half of the 3,3′-dicarboxyl­ato-1,1′-ethyl­enedipyridinium mol­ecule. The Co(II) atom is located on an inversion centre and hence the complex mol­ecule adopts a centrosymmetric trans-octa­hedral geometry. The zwitterionic organic mol­ecule is also centrosymmetric with the centre of the C—C bond of the ethyl­ene moiety coinciding with an inversion centre. The adduct of metal complex and organic mol­ecule is associated into a three-dimenional network through O—H⋯O hydrogen bonds. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011402/ /pubmed/21589255 http://dx.doi.org/10.1107/S1600536810046143 Text en © Wen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Yan-Qing
Tian, Chun-Yan
Gao, En-Qing
Tetra­aqua­diazido­cobalt(II) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium
title Tetra­aqua­diazido­cobalt(II) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium
title_full Tetra­aqua­diazido­cobalt(II) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium
title_fullStr Tetra­aqua­diazido­cobalt(II) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium
title_full_unstemmed Tetra­aqua­diazido­cobalt(II) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium
title_short Tetra­aqua­diazido­cobalt(II) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium
title_sort tetra­aqua­diazido­cobalt(ii) 3,3′-dicarb­oxy­l­ato-1,1′-ethyl­enedipyridinium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011402/
https://www.ncbi.nlm.nih.gov/pubmed/21589255
http://dx.doi.org/10.1107/S1600536810046143
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AT tianchunyan tetraaquadiazidocobaltii33dicarboxylato11ethylenedipyridinium
AT gaoenqing tetraaquadiazidocobaltii33dicarboxylato11ethylenedipyridinium

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