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N,N-Bis(diphenylphosphanyl)cyclopentanamine
The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond an...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011404/ https://www.ncbi.nlm.nih.gov/pubmed/21589599 http://dx.doi.org/10.1107/S1600536810048907 |
Sumario: | The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond angles ranging between 115.22 (12) and 121.76 (9)°. The P atoms present a pyramidal environment with bond angles ranging from 100.62 (9) to 104.71 (8)°. One of the C atoms in the cyclopentyl ring displays a 0.822 (4):0.178 (4) positional disorder. Within the crystal structure, intramolecular C—H⋯P hydrogen bonds together with inter- and intramolecular C—H⋯π interactions link the molecules into a supramolecular two-dimensional network. |
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