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N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine

The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond an...

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Detalles Bibliográficos
Autores principales: Engelbrecht, Ilana, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011404/
https://www.ncbi.nlm.nih.gov/pubmed/21589599
http://dx.doi.org/10.1107/S1600536810048907
Descripción
Sumario:The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond angles ranging between 115.22 (12) and 121.76 (9)°. The P atoms present a pyramidal environment with bond angles ranging from 100.62 (9) to 104.71 (8)°. One of the C atoms in the cyclo­pentyl ring displays a 0.822 (4):0.178 (4) positional disorder. Within the crystal structure, intra­molecular C—H⋯P hydrogen bonds together with inter- and intra­molecular C—H⋯π inter­actions link the mol­ecules into a supra­molecular two-dimensional network.