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N,N-Bis(diphenylphosphanyl)cyclopentanamine
The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond an...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011404/ https://www.ncbi.nlm.nih.gov/pubmed/21589599 http://dx.doi.org/10.1107/S1600536810048907 |
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author | Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas |
author_facet | Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas |
author_sort | Engelbrecht, Ilana |
collection | PubMed |
description | The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond angles ranging between 115.22 (12) and 121.76 (9)°. The P atoms present a pyramidal environment with bond angles ranging from 100.62 (9) to 104.71 (8)°. One of the C atoms in the cyclopentyl ring displays a 0.822 (4):0.178 (4) positional disorder. Within the crystal structure, intramolecular C—H⋯P hydrogen bonds together with inter- and intramolecular C—H⋯π interactions link the molecules into a supramolecular two-dimensional network. |
format | Text |
id | pubmed-3011404 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30114042010-12-30 N,N-Bis(diphenylphosphanyl)cyclopentanamine Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond angles ranging between 115.22 (12) and 121.76 (9)°. The P atoms present a pyramidal environment with bond angles ranging from 100.62 (9) to 104.71 (8)°. One of the C atoms in the cyclopentyl ring displays a 0.822 (4):0.178 (4) positional disorder. Within the crystal structure, intramolecular C—H⋯P hydrogen bonds together with inter- and intramolecular C—H⋯π interactions link the molecules into a supramolecular two-dimensional network. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011404/ /pubmed/21589599 http://dx.doi.org/10.1107/S1600536810048907 Text en © Engelbrecht et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas N,N-Bis(diphenylphosphanyl)cyclopentanamine |
title |
N,N-Bis(diphenylphosphanyl)cyclopentanamine |
title_full |
N,N-Bis(diphenylphosphanyl)cyclopentanamine |
title_fullStr |
N,N-Bis(diphenylphosphanyl)cyclopentanamine |
title_full_unstemmed |
N,N-Bis(diphenylphosphanyl)cyclopentanamine |
title_short |
N,N-Bis(diphenylphosphanyl)cyclopentanamine |
title_sort | n,n-bis(diphenylphosphanyl)cyclopentanamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011404/ https://www.ncbi.nlm.nih.gov/pubmed/21589599 http://dx.doi.org/10.1107/S1600536810048907 |
work_keys_str_mv | AT engelbrechtilana nnbisdiphenylphosphanylcyclopentanamine AT visserhendrikg nnbisdiphenylphosphanylcyclopentanamine AT roodtandreas nnbisdiphenylphosphanylcyclopentanamine |