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N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine

The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond an...

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Autores principales: Engelbrecht, Ilana, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011404/
https://www.ncbi.nlm.nih.gov/pubmed/21589599
http://dx.doi.org/10.1107/S1600536810048907
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author Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_facet Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_sort Engelbrecht, Ilana
collection PubMed
description The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond angles ranging between 115.22 (12) and 121.76 (9)°. The P atoms present a pyramidal environment with bond angles ranging from 100.62 (9) to 104.71 (8)°. One of the C atoms in the cyclo­pentyl ring displays a 0.822 (4):0.178 (4) positional disorder. Within the crystal structure, intra­molecular C—H⋯P hydrogen bonds together with inter- and intra­molecular C—H⋯π inter­actions link the mol­ecules into a supra­molecular two-dimensional network.
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spelling pubmed-30114042010-12-30 N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers The coordination around the N atom in the title compound, C(29)H(29)NP(2), shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal–pyramidal geometry of the N atom is illustrated by the bond angles ranging between 115.22 (12) and 121.76 (9)°. The P atoms present a pyramidal environment with bond angles ranging from 100.62 (9) to 104.71 (8)°. One of the C atoms in the cyclo­pentyl ring displays a 0.822 (4):0.178 (4) positional disorder. Within the crystal structure, intra­molecular C—H⋯P hydrogen bonds together with inter- and intra­molecular C—H⋯π inter­actions link the mol­ecules into a supra­molecular two-dimensional network. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011404/ /pubmed/21589599 http://dx.doi.org/10.1107/S1600536810048907 Text en © Engelbrecht et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine
title N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine
title_full N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine
title_fullStr N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine
title_full_unstemmed N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine
title_short N,N-Bis(diphenyl­phosphan­yl)cyclo­­penta­namine
title_sort n,n-bis(diphenyl­phosphan­yl)cyclo­­penta­namine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011404/
https://www.ncbi.nlm.nih.gov/pubmed/21589599
http://dx.doi.org/10.1107/S1600536810048907
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