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catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] 4,4′-bipyridine disolvate monohydrate]
In the polymeric title complex, {[Ce(C(8)H(7)O(3))(3)(H(2)O)(2)]·2C(10)H(8)N(2)·H(2)O}(n), the Ce(III) ion is coordinated by ten O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and two water molecules. One HPAA ligand coordinates just to one Ce(III) ion, whereas the remaining two bri...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011412/ https://www.ncbi.nlm.nih.gov/pubmed/21589335 http://dx.doi.org/10.1107/S1600536810048166 |
Sumario: | In the polymeric title complex, {[Ce(C(8)H(7)O(3))(3)(H(2)O)(2)]·2C(10)H(8)N(2)·H(2)O}(n), the Ce(III) ion is coordinated by ten O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and two water molecules. One HPAA ligand coordinates just to one Ce(III) ion, whereas the remaining two bridge two Ce(III) ions. The 4,4′-bipyridine molecule and one water molecule are not coordinated to Ce. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link molecules into a three-dimensional network. |
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