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catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] 4,4′-bipyridine disolvate monohydrate]
In the polymeric title complex, {[Ce(C(8)H(7)O(3))(3)(H(2)O)(2)]·2C(10)H(8)N(2)·H(2)O}(n), the Ce(III) ion is coordinated by ten O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and two water molecules. One HPAA ligand coordinates just to one Ce(III) ion, whereas the remaining two bri...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011412/ https://www.ncbi.nlm.nih.gov/pubmed/21589335 http://dx.doi.org/10.1107/S1600536810048166 |
| _version_ | 1782194934706601984 |
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| author | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
| author_facet | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
| author_sort | Liu, Jia-Lu |
| collection | PubMed |
| description | In the polymeric title complex, {[Ce(C(8)H(7)O(3))(3)(H(2)O)(2)]·2C(10)H(8)N(2)·H(2)O}(n), the Ce(III) ion is coordinated by ten O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and two water molecules. One HPAA ligand coordinates just to one Ce(III) ion, whereas the remaining two bridge two Ce(III) ions. The 4,4′-bipyridine molecule and one water molecule are not coordinated to Ce. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link molecules into a three-dimensional network. |
| format | Text |
| id | pubmed-3011412 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30114122010-12-30 catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] 4,4′-bipyridine disolvate monohydrate] Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, {[Ce(C(8)H(7)O(3))(3)(H(2)O)(2)]·2C(10)H(8)N(2)·H(2)O}(n), the Ce(III) ion is coordinated by ten O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and two water molecules. One HPAA ligand coordinates just to one Ce(III) ion, whereas the remaining two bridge two Ce(III) ions. The 4,4′-bipyridine molecule and one water molecule are not coordinated to Ce. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link molecules into a three-dimensional network. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011412/ /pubmed/21589335 http://dx.doi.org/10.1107/S1600536810048166 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] 4,4′-bipyridine disolvate monohydrate] |
| title |
catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] 4,4′-bipyridine disolvate monohydrate] |
| title_full |
catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] 4,4′-bipyridine disolvate monohydrate] |
| title_fullStr |
catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] 4,4′-bipyridine disolvate monohydrate] |
| title_full_unstemmed |
catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] 4,4′-bipyridine disolvate monohydrate] |
| title_short |
catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] 4,4′-bipyridine disolvate monohydrate] |
| title_sort | catena-poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ(2)
o,o′]cerium(iii)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
o,o′:o;κ(3)
o:o,o′] 4,4′-bipyridine disolvate monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011412/ https://www.ncbi.nlm.nih.gov/pubmed/21589335 http://dx.doi.org/10.1107/S1600536810048166 |
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